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Silver nitrate

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Name

Silver nitrate

EINECS 231-853-9
CAS No. 7761-88-8 Density 4.35 g/cm3
PSA 68.88000 LogP 0.28410
Solubility 219 g/100 mL (20 °C) in water Melting Point 212 °C (dec.)(lit.)
Formula AgNO3 Boiling Point 444 °C
Molecular Weight 169.873 Flash Point 40 °C
Transport Information UN 1493 5.1/PG 2 Appearance colorless or white crystalline solid
Safety 26-45-60-61-36/37/39-27 Risk Codes 34-50/53-8-36/38-51/53-52/53-35-10-40-20/22
Molecular Structure Molecular Structure of 7761-88-8 (Silver nitrate) Hazard Symbols OxidizingO,CorrosiveC,DangerousN,IrritantXi
Synonyms

Silvernitrate;Nitricacid silver(1+) salt (8CI,9CI);Silver nitrate (7CI);Nitric acid silver(I)salt;Nitric acid, silver(1+) salt;Silver (I) nitrate;Silver mononitrate;Silver(1+) nitrate;

Article Data 1

Silver nitrate History

Albertus Magnus, in the 13th century, documented the ability of nitric acid to separate gold and silver by dissolving the silver.Magnus noted that the resulting solution of silver nitrate could blacken skin.

Silver nitrate Specification

The IUPAC name of Silver nitrate is silver nitrate. With the CAS registry number 7761-88-8, it is also named as Nitric acid, silver(1+) salt. The product's categories are Inorganics; Amino Alcohols Chemical Synthesis; Organic Building Blocks; Oxygen Compounds; SVolumetric Solutions; Metal and Ceramic Science; Salts; Silver Salts; Nitrate Alphabetic; Application CRMs; ICP CRMs Spectroscopy; ICP-OES/-MS; ICP Spectroscopy; Matrix Selection; SA - SM; Reference Material Sodium Chloride Volumetric Solutions; S - ZTitration; Solution Containers (VOLPAC); S - Z; Salt Solutions; Concentrates (e.g. FIXANAL); Salt Concentrates; Biomolecular MS; Core Bioreagents; Reagents and Supplements; Pharmacopoeia A-Z; Reagent PlusStains and Dyes; Pharmacopoeia (USP); Pharmacopoeia A-Z Pharmacopoeia (USP); ACS Grade Chemical Synthesis, etc., and the other registry numbers are 31890-20-7; 8012-12-2. Besides, it is colorless or white crystalline solid, which should be stored in a dark. cool, ventilated warehouse at 2-8 °C away from fire and heat source. In addition, its molecular formula is AgNO3 and molecular weight is 169.87.

The other characteristics of this product can be summarized as: (1)H-Bond Donor: 0; (2)H-Bond Acceptor: 3; (3)Rotatable Bond Count: 0; (4)Exact Mass: 168.892911; (5)MonoIsotopic Mass: 168.892911; (6)Topological Polar Surface Area: 62.9; (7)Heavy Atom Count: 5; (8)Complexity: 18.8; (9)EINECS: 231-853-9; (10)Density: 4.35 g/cm3; (11)Vapor Density: 5.8 (vs air); (12)Melting point: 212 °C; (13)Boiling point: 444 °C; (14)Flash Point: 40 °C; (15)Water solubility: 219 g/100 mL (20 °C).

Preparation of Silver nitrate: this chemical can be prepared by reacting silver with nitric acid:
Ag + 2 HNO3 → AgNO3 + NO2 + H2O
This reaction should be performed under a fume hood.

Uses of Silver nitrate: When making photographic film, this chemical can be used to to form insoluble silver halide by treating with halide salts of sodium or potassium in situ in photographic gelatin, which is then applied to strips of tri-acetate or polyester. It is also used to prepare some silver-based explosives. And it can be used to separate mixtures of alkenes by selective absorption. It is used in histology to stain silver, which is used for demonstrating reticular fibers, proteins and nucleic acids. It also can be used in scanning electron microscopy as a stain. Similarly, this product can be used as an antimicrobial. Furthermore, it can be used to produce dark grey Silver oxide:
2 AgNO3 + 2 NaOH → Ag2O + 2 NaNO3 + H2O

When you are using this chemical, please be cautious about it as the following: it is flammable that may cause severe burns in contact with combustible material. Moreover, it is harmful by inhalation and if swallowed. And it is irritating to eyes and skin. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Additionally, you should wear suitable protective clothing, gloves and eye/face protection. Please take off all contaminated clothing immediately. In case of accident or if you feel unwell, please seek medical advice immediately (show the label whenever possible). Limited evidence of a carcinogenic effect. What's more, it is harmful  and very toxic to aquatic organisms that may cause long-term adverse effects in the aquatic environment. This material and its container must be disposed of as hazardous waste. And you should avoid release to the environment. Refer to special instructions / safety data sheets.

People can use the following data to convert to the molecule structure.
(1)SMILES: [N+](=O)([O-])[O-].[Ag+]
(2)InChI: InChI=1/Ag.NO3/c;2-1(3)4/q+1;-1
(3)InChIKey: SQGYOTSLMSWVJD-UHFFFAOYAW
(4)Std. InChI: InChI=1S/Ag.NO3/c;2-1(3)4/q+1;-1
(5)Std. InChIKey: SQGYOTSLMSWVJD-UHFFFAOYSA-N

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
dog LDLo oral 20mg/kg (20mg/kg)   "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1289, 1935.
guinea pig LD50 oral 473mg/kg (473mg/kg) BEHAVIORAL: TETANY

GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"

LUNGS, THORAX, OR RESPIRATION: CYANOSIS
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 27(12), Pg. 33, 1983.
guinea pig LDLo intraperitoneal 216mg/kg (216mg/kg)   Archives of Environmental Health. Vol. 11, Pg. 201, 1965.
guinea pig LDLo subcutaneous 62mg/kg (62mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"
British Medical Journal. Vol. 2, Pg. 217, 1913.
man LDLo unreported 29mg/kg (29mg/kg)   "Poisoning; Toxicology, Symptoms, Treatments," 2nd ed., Arena, J.M., Springfield, IL, C.C. Thomas, 1970Vol. 2, Pg. 73, 1970.
mouse LD50 intraperitoneal 17mg/kg (17mg/kg)   Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 27(12), Pg. 33, 1983.
mouse LD50 oral 50mg/kg (50mg/kg)   Journal of Pharmacy and Pharmacology. Vol. 2, Pg. 20, 1950.
rabbit LDLo intravenous 8800ug/kg (8.8mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
rabbit LDLo oral 800mg/kg (800mg/kg)   "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1289, 1935.
rat LD50 intraperitoneal 83mg/kg (83mg/kg)   Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 27(12), Pg. 33, 1983.
rat LD50 oral 1173mg/kg (1173mg/kg) BEHAVIORAL: TETANY

LUNGS, THORAX, OR RESPIRATION: CYANOSIS

GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 27(12), Pg. 33, 1983.