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Sodium propan-2-olate

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Name

Sodium propan-2-olate

EINECS 211-673-7
CAS No. 683-60-3 Density 0.9 g/cm3
PSA 23.06000 LogP 0.82530
Solubility N/A Melting Point 70-75 °C
Formula C3H7NaO Boiling Point 73°C at 760 mmHg
Molecular Weight 82.0777 Flash Point -19°C
Transport Information N/A Appearance Yellow-brown crystals similar to alcohol
Safety 16-26-43-45 Risk Codes 11-34-41
Molecular Structure Molecular Structure of 683-60-3 (Sodium propan-2-olate) Hazard Symbols C,F
Synonyms

2-Propanol,sodium salt (9CI);Isopropyl alcohol, sodium salt (8CI);Sodium isopropoxide(6CI,7CI);Isopropanol sodium salt;Isopropoxysodium;Sodium isopropanolate;Sodium isopropyl oxide;Sodium isopropylate;

Article Data 34

Sodium propan-2-olate Synthetic route

108-20-3

di-isopropyl ether

1822-71-5

n-pentylsodium

A

683-60-3

sodium isopropylate

B

2521-40-6

allyl sodium

Conditions
ConditionsYield
With pentane
108-20-3

di-isopropyl ether

1822-71-5

n-pentylsodium

109-66-0

pentane

A

683-60-3

sodium isopropylate

B

2521-40-6

allyl sodium

C9H10N3O5(1-)*Na(1+)

A

683-60-3

sodium isopropylate

B

18771-85-2

4-nitrobenzofuroxan

Conditions
ConditionsYield
In isopropyl alcohol at 15 - 35℃; Kinetics;
In isopropyl alcohol at 25℃; Equilibrium constant; Thermodynamic data; ΔH(excit.), ΔS(excit.);

C12H17N2O6(1-)*Na(1+)

A

10242-16-7

2,4-dinitrophenyl isopropyl ether

B

683-60-3

sodium isopropylate

Conditions
ConditionsYield
In isopropyl alcohol at 25℃; Equilibrium constant;

C12H16ClN2O6(1-)*Na(1+)

A

71338-03-9

6-Chlor-1-isopropoxy-2,4-dinitrobenzol

B

683-60-3

sodium isopropylate

Conditions
ConditionsYield
In isopropyl alcohol at 25℃; Equilibrium constant;

C16H23N2O8(1-)*Na(1+)

A

71338-04-0

1-Isopropoxy-6-isopropoxycarbonyl-2,4-dinitrobenzol

B

683-60-3

sodium isopropylate

Conditions
ConditionsYield
In isopropyl alcohol at 25℃; Equilibrium constant;

C12H16N3O8(1-)*Na(1+)

A

10242-23-6

2,4,6-trinitrophenyl isopropyl ether

B

683-60-3

sodium isopropylate

Conditions
ConditionsYield
With sodium perchlorate In isopropyl alcohol at 25℃; Equilibrium constant;
67-63-0

isopropyl alcohol

683-60-3

sodium isopropylate

Conditions
ConditionsYield
With sodium at 60 - 90℃; for 1h; Product distribution / selectivity;
With sodium hydride at 0℃;
With sodium hydride
2996-92-1

phenyl trimethylsiloxane

67-63-0

isopropyl alcohol

A

sodium-bond phenylsilsesquioxane

B

tetrasodium salt of double-decker phenylsilsesquioxane

C

683-60-3

sodium isopropylate

Conditions
ConditionsYield
With sodium hydroxide In water at 20℃; for 4.25h; Reflux; Overall yield = 22.15 g;
683-60-3

sodium isopropylate

81171-31-5

[2-Chloro-1-methyl-2-phenyl-eth-(E)-ylidene]-isopropyl-amine

103818-65-1

isopropyl N-isopropyl-3-phenylpropanimidate

Conditions
ConditionsYield
In isopropyl alcohol for 18h; Heating;100%

Sodium propan-2-olate Specification

The IUPAC name of Sodium isopropoxide is sodium propan-2-olate. With the CAS registry number 683-60-3, it is also named as 2-Propanol, sodium salt. It is yellow-brown crystals similar to alcohol which reacts strong with water. Additionally, this chemical can be obtained by the reaction of  metallic sodium and dried isopropanol. It should be stored in a container which is filled dry inert gas. And the container is placed in the cool and dry aera. When heated to decomposition it emits toxic fumes of Na2O.

The other characteristics of this product can be summarized as: (1)H-Bond Donor: 0; (2)H-Bond Acceptor: 1; (3)Rotatable Bond Count: 0; (4)Exact Mass: 82.03946; (5)MonoIsotopic Mass: 82.03946; (6)Topological Polar Surface Area: 23.1; (7)Heavy Atom Count: 5; (8)Complexity: 14.4; (9)Covalently-Bonded Unit Count: 2.

Uses of Sodium isopropoxide: It is used as Ibuprofen intermediate. And in many reactions such as polymerization of butadiene, it used as a catalyst. Additionally, Sodium isopropoxide is used in the manufacture of acetone and its derivatives and as a solvent. Topically, it is used as an antiseptic. 

When you are using this chemical, please be cautious about it as the following:
It is highly flammable, so people should keep it away from sources of ignition. And it can cause burns and has risk of serious damage to the eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)

People can use the following data to convert to the molecule structure.
1. SMILES:CC(C)O[Na]
2. InChI:InChI=1/C3H7O.Na/c1-3(2)4;/h3H,1-2H3;/q-1;+1/rC3H7NaO/c1-3(2)5-4/h3H,1-2H3

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