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TETRADECYL PHOSPHONIC ACID

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Name

TETRADECYL PHOSPHONIC ACID

EINECS 225-118-1
CAS No. 4671-75-4 Density 0.998 g/cm3
PSA 67.34000 LogP 4.86520
Solubility Soluble in ethanol, dimethyl sulfoxide and dimethyl formamide. Partially soluble in water. Melting Point 96-98ºC
Formula C14H31 O3 P Boiling Point 411.2 °C at 760 mmHg
Molecular Weight 278.372 Flash Point 202.5 °C
Transport Information N/A Appearance white to off-white powder
Safety Moderately toxic by ingestion. When heated to decomposition it emits toxic fumes of POx. Risk Codes 36/37/38
Molecular Structure Molecular Structure of 4671-75-4 (N-TETRADECYLPHOSPHONIC ACID) Hazard Symbols N/A
Synonyms

Phosphonicacid, tetradecyl- (7CI,8CI,9CI); 1-Tetradecanephosphonic acid; TDPA;Tetradecanephosphonic acid; Tetradecylphosphonic acid; n-Tetradecylphosphonicacid

Article Data 5

TETRADECYL PHOSPHONIC ACID Synthetic route

112-71-0

1-Bromotetradecane

4671-75-4

n-tetradecylphosphonic acid

Conditions
ConditionsYield
Stage #1: 1-Bromotetradecane With potassium hydroxide semihydrate; phosphorus; cetyltrimethylammonim bromide In water; toluene at 85 - 90℃; for 6h; Inert atmosphere;
Stage #2: With nitric acid In water at 100 - 110℃; for 2h; pH=4; Inert atmosphere;
50%
Multi-step reaction with 2 steps
1: hexane
2: concentrated aqueous HCl
View Scheme
33512-29-7

tetradecyl-phosphonic acid dibutyl ester

4671-75-4

n-tetradecylphosphonic acid

Conditions
ConditionsYield
With hydrogenchloride
75-21-8

oxirane

4671-75-4

n-tetradecylphosphonic acid

59259-21-1

O-β-Hydroxyaethyl-1-n-tetradecylphosphonat

Conditions
ConditionsYield
In benzene
4671-75-4

n-tetradecylphosphonic acid

76742-18-2

cytidine 5'-monophosphomorpholidate 4-morpholine-N,N'-dicyclohexylcarboxamidine salt

C23H43N3O10P2

Conditions
ConditionsYield
With pyridine at 25 - 35℃; for 80h;
4671-75-4

n-tetradecylphosphonic acid

7722-84-1

dihydrogen peroxide

71-43-2

benzene

MoO3

MoO3

compound C28H60MoO10P2

compound C28H60MoO10P2

4671-75-4

n-tetradecylphosphonic acid

7722-84-1

dihydrogen peroxide

71-43-2

benzene

MoO3

MoO3

compound C28H60MoO8P2

compound C28H60MoO8P2

Conditions
ConditionsYield
at 130℃;
4671-75-4

n-tetradecylphosphonic acid

59259-19-7

O-Methyl-O-β-hydroxyaethyl-tetradecylphosphonat

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: benzene
View Scheme
4671-75-4

n-tetradecylphosphonic acid

40520-22-7

Di-O-β-hydroxyaethyl-n-tetradecyl-1-phosphonat

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: benzene
3: benzene
View Scheme
4671-75-4

n-tetradecylphosphonic acid

cobalt acetylacetonate

cobalt(III) phosphide

Conditions
ConditionsYield
In further solvent(s) mixt. hexadecylamine and trioctylphosphine was heated at 140°C under vac. for 1 h, Co(acac)2 and tetradecylphosphonic acid were added at 100°C, stirred under N2, slowly heated to 340°C over 1 h, mixt. was kept at this temp. for 3 h; mixt. was cooled to 60°C, excess EtOH was added. ppt. was separeted by centrifugation, dried under vac.;
4671-75-4

n-tetradecylphosphonic acid

142-71-2

copper diacetate

Cu(2+)*CH3(CH2)13PO3(2-)=Cu(CH3(CH2)13PO3)

Conditions
ConditionsYield
In ethanol; water aq. soln. of CuCl2 added dropwise to soln. of acid in H2O/EtOH (3/1, v/v) (1:1 molar ratio), mixt. stirred overnight at 70°C; filtered off, washed (H2O, EtOH), dried at room temp.;

TETRADECYL PHOSPHONIC ACID Chemical Properties

IUPAC Name: Tetradecylphosphonic acid
Synonyms: Tdpa;tetradecyl phosphonate ; Tetradecylphosphonic acid ; N-tetradecylphosphonic acid ; 1-Tetradecanephosphonic acid ; Tetradecanephosphonicacid ; Tetradecyl-phosphonicaci ; N-Tetradecylphosphonicacid,98%
CAS: 4671-75-4
Molecular Formula of Tetradecyl phosphonic acid (4671-75-4) : C14H31O3P
Molecular Weight of Tetradecyl phosphonic acid (4671-75-4) : 278.37
Molecular Struture of Tetradecyl phosphonic acid (4671-75-4) : 
EINECS: 225-118-1
Product Categories: 
Mol File: 4671-75-4.mol
Surface Tension: 38.5 dyne/cm 
Density: 0.998 g/cm
Flash Point: 202.5 °C 
Enthalpy of Vaporization: 72.81 kJ/mol 
Boiling Point: 411.2 °C at 760 mmHg 
Vapour Pressure: 6.51E-08 mmHg at 25°C 
Index of Refraction: 1.463 

TETRADECYL PHOSPHONIC ACID Toxicity Data With Reference

1.    

orl-mus LD50:2100 mg/kg

    AMIHAB    AMA Archives of Industrial Health. 11 (1955),487.

TETRADECYL PHOSPHONIC ACID Consensus Reports

Reported in EPA TSCA Inventory.

TETRADECYL PHOSPHONIC ACID Safety Profile

Risk Statements  36/37/38
36/37/38:  Irritating to eyes, respiratory system and skin  
Safety Statements  26-36/37/39
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 
36/37/39:  Wear suitable protective clothing, gloves and eye/face protection 

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