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Telluric acid

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Name

Telluric acid

EINECS 232-267-6
CAS No. 7803-68-1 Density g/cm3
PSA 121.38000 LogP -1.44160
Solubility N/A Melting Point N/A
Formula H6O6 Te Boiling Point °Cat760mmHg
Molecular Weight 229.644 Flash Point °C
Transport Information N/A Appearance N/A
Safety Poison by ingestion and intravenous routes. When heated to decomposition it emits toxic fumes of Te. See also TELLURIUM COMPOUNDS. Risk Codes R20
Molecular Structure Molecular Structure of 7803-68-1 (Orthotelluric acid) Hazard Symbols As for tellurium.
Synonyms

Telluric(VI)acid (H6TeO6) (6CI,7CI);Hydrogen tellurate (H6TeO6);Orthotelluric acid;Tellurium hexahydroxide;Tellurium hydroxide (Te(OH)6);

Article Data 113

Telluric acid Synthetic route

tellurium

A

B

Conditions
ConditionsYield
In water oxidation;;A 0%
B n/a
In water very slow oxidation;;A 0%
B n/a

Telluric acid Chemical Properties

Molecule structure of Telluric acid (CAS NO.7803-68-1) :

Molecular Weight: 229.64404 g/mol
Molecular Formula: H6O6Te 
Solubility: H2O: 0.1 g/mL, clear, colorless
Merck: 13.9200
H-Bond Donor: 6
H-Bond Acceptor: 6
Exact Mass: 231.922661
MonoIsotopic Mass: 231.922661
Topological Polar Surface Area: 121
Heavy Atom Count: 7 
Complexity: 62.7 
Canonical SMILES: O[Te](O)(O)(O)(O)O
InChI: InChI=1S/H6O6Te/c1-7(2,3,4,5)6/h1-6H
InChIKey: FXADMRZICBQPQY-UHFFFAOYSA-N
EINECS: 232-267-6
Product Categories of Telluric acid (CAS NO.7803-68-1) : Acids; Electronic Chemicals; Micro/Nanoelectronics

Telluric acid Production

 Telluric acid is formed by the oxidation of tellurium or tellurium dioxide with a powerful oxidising agent such as hydrogen peroxide, chromium trioxide or sodium peroxide.
TeO2 + H2O2 + 2H2O → Te(OH)6
Crystallisation of telluric acid solutions below 10 °C gives Te(OH)6.4H2O. It is oxidizing, as shown by the electrode potential for the reaction below, although it is kinetically slow in its oxidations.
H6TeO6 + 2H+ + 2e− TeO2 + 4H2O Eo = +1.02 V

Telluric acid Toxicity Data With Reference

1.    

ivn-rat LDLo:31 mg/kg

    JPETAB    Journal of Pharmacology and Experimental Therapeutics. 33 (1928),270.
2.    

orl-rbt LDLo:56 mg/kg

    JPETAB    Journal of Pharmacology and Experimental Therapeutics. 33 (1928),270.
3.    

ivn-rbt LDLo:5600 µg/kg

    JPETAB    Journal of Pharmacology and Experimental Therapeutics. 33 (1928),270.

Telluric acid Consensus Reports

Reported in EPA TSCA Inventory.

Telluric acid Safety Profile

Poison by ingestion and intravenous routes. When heated to decomposition it emits toxic fumes of Te. See also TELLURIUM COMPOUNDS.
Hazard Codes:HarmfulXn
Risk Statements: 20 
R20:Harmful by inhalation.
Safety Statements: 22-36/37/39-38 
S22:Do not breathe dust. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 
S38:In case of insufficient ventilation, wear suitable respiratory equipment.
RIDADR UN: 3284 6.1/PG 3
WGK Germany: 3
RTECS: WY2350000
F: 8
HazardClass: 6.1(a)
PackingGroup: II

Telluric acid Standards and Recommendations

OSHA PEL: TWA 0.1 mg(Te)/m3
ACGIH TLV: TWA 0.1 mg(Te)/m3

Telluric acid Specification

 Telluric acid (CAS NO.7803-68-1) is also called Telluric(VI) acid ; CCRIS 9168 ; Orthotelluric acid ; Tellurate ; Tellurium hydroxide ; Telluric acid (H6TeO6) .The anhydrous acid of  Telluric acid (CAS NO.7803-68-1) is stable in air at 100 °C but above this it dehydrates to form polymetatelluric acid, a white hygroscopic powder (approximate composition (H2TeO4)10), and allotelluric acid, an acid syrup of unknown structure (approximate composition (H2TeO4)3(H2O)4). Strong heating at over 300 °C produces the α- crystalline modification of tellurium trioxide, α-TeO3.
Reaction with diazomethane gives the hexamethyl ester, Te(OMe)6. Telluric acid and its salts mostly contain hexacoordinate tellurium. This is true even for salts such as magnesium tellurate, MgTeO4, which is isostructural with magnesium molybdate and contains TeO6 octahedra.

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