Welcome to LookChem.com Sign In|Join Free
  • or
Home > Products >  > 

Thiacloprid

Related Products

Hot Products

Name

Thiacloprid

EINECS N/A
CAS No. 111988-49-9 Density 1.42 g/cm3
PSA 77.58000 LogP 2.05878
Solubility 185mg/L (20°C) in water Melting Point 136oC
Formula C10H9ClN4S Boiling Point 423.1 °C at 760 mmHg
Molecular Weight 252.727 Flash Point 209.7 °C
Transport Information 2588 Appearance yellowish crystalline powder
Safety 60 Risk Codes 20/22-52/53
Molecular Structure Molecular Structure of 111988-49-9 (Thiacloprid) Hazard Symbols HarmfulXn
Synonyms

Cyanamide,[3-[(6-chloro-3-pyridinyl)methyl]-2-thiazolidinylidene]-, [N(Z)]- (9CI);Bariard;Biscaya;Calypso;Calypso (pesticide);Calypso 70WG;Calypso Ultra;

Article Data 8

Thiacloprid Specification

The IUPAC name of (3-((6-Chloro-3-pyridinyl)methyl)-2-thiazolidinylidene)cyanamide is [3-[(6-chloropyridin-3-yl)methyl]-1,3-thiazolidin-2-ylidene]cyanamide. With the CAS registry number 111988-49-9, it is also named as Thiacloprid [ISO:BSI]. It is yellowish crystalline powder which is stable under normal temperature and pressure. Additionally, this chemical should be sealed in the container and stored in the cool and dry place.

The other characteristics of this product can be summarized as: (1)ACD/LogP: 0.55; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 0.55; (4)ACD/LogD (pH 7.4): 0.55; (5)ACD/BCF (pH 5.5): 1.54; (6)ACD/BCF (pH 7.4): 1.54; (7)ACD/KOC (pH 5.5): 47.47; (8)ACD/KOC (pH 7.4): 47.47; (9)#H bond acceptors: 4; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 2; (12)Index of Refraction: 1.691; (13)Molar Refractivity: 67.92 cm3; (14)Molar Volume: 177.4 cm3; (15)Polarizability: 26.92×10-24 cm3; (16)Surface Tension: 58.1 dyne/cm; (17)Enthalpy of Vaporization: 67.73 kJ/mol; (18)Vapour Pressure: 2.3E-07 mmHg at 25°C; (19)Rotatable Bond Count: 2; (20)Exact Mass: 252.023645; (21)MonoIsotopic Mass: 252.023645; (22)Topological Polar Surface Area: 77.6; (23)Heavy Atom Count: 16; (24)Complexity: 324.

Preparation of (3-((6-Chloro-3-pyridinyl)methyl)-2-thiazolidinylidene)cyanamide: Adding 2.0g N-(2-chloro-5-pyridylmethyl)-cysteamine and 1.3g dimethyl cyanodithioimidoacrbonate to 50mL ethanol. Under nitrogen atmosphere, the mixture stirs and refluxs 8h. After the reaction, vacuum distillation to remove about 2 / 3 ethanol, standing at room temperature for product crystallization. After filtration, washing with ether and drying, we can get the product.

Uses of (3-((6-Chloro-3-pyridinyl)methyl)-2-thiazolidinylidene)cyanamide: It is broad-spectrum and systemic insecticide which is mainly used to control most of the pests for rice, fruits, vegetables and cotton.

When you are using this chemical, please be cautious about it as the following:
It is not only harmful by inhalation and if swallowed, but also very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. This material and its container must be disposed of as hazardous waste.

People can use the following data to convert to the molecule structure.
1. SMILES:Clc1ncc(cc1)CN2C(=N\C#N)\SCC2
2. InChI:InChI=1/C10H9ClN4S/c11-9-2-1-8(5-13-9)6-15-3-4-16-10(15)14-7-12/h1-2,5H,3-4,6H2/b14-10-
3. InChIKey:HOKKPVIRMVDYPB-UVTDQMKNBC

The following are the toxicity data which has been tested.

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rat LC50 inhalation 1223mg/m3/4H (1223mg/m3) BEHAVIORAL: TREMOR

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS
National Technical Information Service. Vol. OTS0559691,
rat LD50 oral 444mg/kg (444mg/kg) BEHAVIORAL: TREMOR

GASTROINTESTINAL: DECREASED MOTILITY OR CONSTIPATION

SKIN AND APPENDAGES (SKIN): HAIR: OTHER
National Technical Information Service. Vol. OTS0559690,

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 111988-49-9