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Name |
Titanium tetraiodide |
EINECS | 231-754-0 |
CAS No. | 7720-83-4 | Density | 4.3 g/cm3 |
PSA | 0.00000 | LogP | 3.54280 |
Solubility | hydrolysis in water, soluble in benzene and carbon disulfide | Melting Point |
150-151 °C |
Formula | I4Ti | Boiling Point | 377.1 °C at 760 mmHg |
Molecular Weight | 555.498 | Flash Point | N/A |
Transport Information | UN 3260 | Appearance | purple to black fused solid |
Safety | 26-36/37/39-45 | Risk Codes | 34-37 |
Molecular Structure | Hazard Symbols | C | |
Synonyms |
Titaniumiodide (TiI4) (6CI,8CI);Tetraiodotitanium;Titanium(IV)iodide; |
Article Data | 26 |
The Titanium tetraiodide, with the CAS registry number 7720-83-4, is also known as Titanium (IV) iodide. It is a rare molecular binary metal iodide, consisting of isolated molecules of tetrahedral Ti(IV) centers. Its EINECS registry number is 231-754-0. This chemical's molecular formula is I4Ti and molecular weight is 555.48. What's more, its IUPAC name is Tetraiodotitanium. In addition, it must be stored in airtight containers under the protection of dry gas and placed in a dry, cool place. Meanwhile, it should avoid contact with moisture.
Physical properties about Titanium tetraiodide are: (1)H-Bond Donor: 0; (2)H-Bond Acceptor: 0; (3)Rotatable Bond Count: 0; (4)Exact Mass: 555.565819; (5)MonoIsotopic Mass: 555.565819; (6)Topological Polar Surface Area: 0; (7)Heavy Atom Count: 5; (8)Formal Charge: 0; (9)Complexity: 19.1; (10)Isotope Atom Count: 0; (11)Defined Atom StereoCenter Count: 0; (12)Undefined Atom StereoCenter Count: 0; (13)Defined Bond StereoCenter Count: 0; (14)Undefined Bond StereoCenter Count: 0; (15)Covalently-Bonded Unit Count: 1.
Preparation of Titanium tetraiodide:
1) From the elements, typically using a tube furnace at 425 °C. On the other hand, this reaction can be reversed to produce highly pure films of Ti metal.
Ti + 2 I2 → TiI4
2) Exchange reaction from titanium tetrachloride and HI.
TiCl4 + 4 HI → TiI4 + 4 HCl
3) Oxide-iodide exchange from Aluminium iodide.
3 TiO2 + 4 AlI3 → 3 TiI4 + 2 Al2O3
When you are using this chemical, please be cautious about it as the following:
As a chemical, it is irritating to respiratory system. In addition, this chemical may cause burns. During using it, wear suitable protective clothing, gloves and eye/face protection. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
You can still convert the following datas into molecular structure:
(1) Canonical SMILES: [Ti](I)(I)(I)I
(2) InChI: InChI=1S/4HI.Ti/h4*1H;/q;;;;+4/p-4
(3) InChIKey: NLLZTRMHNHVXJJ-UHFFFAOYSA-J