In the excited state, the ketone molecule undergoes a β-cleavage reaction. β-cleavage is a chemical reaction where a bond is cleaved at the β-carbon (the carbon next to the carbonyl group). This cleavage results in the formation of a xanthyl cation and a radical species.
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rac-9-(1'-ethoxycarbonyl-2'-phenyl-2'-oxoeth-1'-yl)xanthene
