Fluorine is a strong and relatively inert element, so breaking C-F bonds can be challenging. Iridium porphyrins, as well as other transition metal complexes, can facilitate the activation of C-F bonds through processes such as oxidative addition. The iridium center interacts with the fluorine atom in the C-F bond, weakening the bond and making it more susceptible to cleavage.
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phenyl(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III)
