The dirhodium(II) catalyst can generate a metal-bound carbene or carbenoid species, which is highly reactive and can insert into a nearby C-H bond. In this case, it would be the C-H bond adjacent to the sulfur atom.
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Butanoic acid, 3-oxo-, 1-phenyl-2-propenyl ester
5,6,7-trimethoxy-3-(4-methoxyphenyl)-1,2-dihydronaphthalene
