Chiral Lewis acids are a class of compounds that can coordinate with electron pairs and are chiral in nature. They play a critical role in asymmetric synthesis by facilitating reactions in a stereoselective manner. In the context of ATRC, chiral Lewis acids can be used to control the stereochemistry of the radical cyclization reaction.
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ethyl 6α-propyl-1β-methyl-2-oxocyclohexane-1α-carboxylate
(2R,5R)-2-Hydroxymethyl-5-phenyl-tetrahydro-pyran-3-ol
