This term refers to the formation of a metal-carbon bond within a cyclic ligand framework. In the context of ruthenium complexes, cyclometalation often involves the formation of a metal-carbon bond on the aromatic ring of the aryl substituent.
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[RuH(CO)(CH3OC6H4NC(O)C5H4N)(P(C6H5)3)2]
[(2-tert-butyl-6-(4-fluorophenyl)pyridine(-2H))Pt(PPh3)]
di-μ-chloro-bis[1-(3'-methoxyphenyazo)naphthyl-C(2),Nβ]dipalladium(II)
tetramethylammonium 4-(dimethylamino)benzoate
