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Chemical Baike

Diastereoselective Reaction

The reaction is described as "extremely high diastereoselective," meaning it favors the formation of one diastereomer over the other to an exceptional degree. In this context, the reaction involves the addition of the chiral titanium ate complex to the arylcarbaldehydes, leading to the formation of (R)- and (S)-3-arylphthalides.

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