The use of alkylidenecyclopropane amino acid derivatives suggests a novel and efficient approach for building the 6H-pyrrolo[3,4-b]pyridine skeleton. The efficiency may be related to the reactivity of alkylidenecyclopropanes and the ability to incorporate them into the amino acid structure.
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(2S)-2-[N-(2-cyclopropylideneethyl)-N-tosylamino]propanal
2-fluoro-5-(6-nitropyridin-3-yloxy)benzenamine
