In the initial step, a substrate with a suitable functional group is treated with an iodide source, typically iodide ions (I-). The iodide can act as a nucleophile, attacking an electrophilic center on the substrate to form a new carbon-iodine bond. This can lead to the formation of a cyclic intermediate.
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2,2-Dimethyl-but-3-enoic acid (2-chloro-benzyl)-hydroxy-amide
l-2-(2-menthyl)pyridine
