Rhodium porphyrin radicals can also react with diazo compounds to generate metal-bound nitrenes. These nitrenes can be transferred to other substrates, leading to a variety of nitrene transfer reactions, including amination, aziridination, and C-H insertion reactions.
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ethyl (5,10,15,20-tetramesitylporphyrinato)rhodium(III) acetate
3-isopropyl-1,4,2-dioxazole-5-one
