Precursor complex

An initial metal-ligand complex that undergoes further reactions to form the desired product.

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Reactions of a platinum(II) agostic complex: Decyclometalation, dicyclometalation, and solvent-switchable formation of a rollover complex
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Improved one-pot synthesis of second-generation ruthenium olefin metathesis catalysts
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Elemental analysis Regioselectivity Diastereoselectivity Green chemistry Microwave-assisted synthesis Column chromatography Crystallization Yield NMR spectroscopy Decomposition Isolation Mass spectrometry Selectivity Hydrogenation Enantioselectivity Steric hindrance Chromatography Mass spectrometry (MS) Atom economy one-pot synthesis Cross-coupling Electrochemistry TLC (thin-layer chromatography) Self-assembly Dehydrogenation catalyst recycling X-ray crystallography Chelation Metathesis Isomerization Ligand Design Catalytic Reaction Workup Steric Effects Oxidative Addition Reductive Elimination Chemoselectivity Reaction Mechanism Electronic effects Reaction Kinetics Substrate Scope Solvent Effects Substituent Effects Computational Modeling Catalyst Loading Reaction Monitoring Transmetalation Carbonylation Homolytic Cleavage Heterolytic Cleavage

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