Trifluoromethylthiolation involves the introduction of a trifluoromethylthio group (-SCF3) onto a molecule. This reaction is typically carried out using reagents that contain a trifluoromethylthiolating group such as Rongalite (sodium dithionite) and an appropriate source of CF3S. The reaction with β,γ-unsaturated hydrazones would typically involve the addition of the -SCF3 group to the carbon atoms in the β or γ positions of the hydrazone. The exact conditions and reagents may vary depending on the specific compound and desired regioselectivity.
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2,2-dimethyl-1-(3-methoxy phenyl)-3-butene-1-one
6-BROMO-8-METHOXY-2-OXO-2H-CHROMENE-3-CARBOXYLIC ACID
4-(2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)ethyl)benzonitrile
1-methoxy-4-{[(trifluoromethyl)sulfanyl]methyl}benzene
((2-(2',6'-dichloro-4-iodo-3',4',5'-trimethoxy-[1,1'-biphenyl]-3-yl)propan-2-yl)oxy)(trifluoromethyl)sulfane
