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10028-15-6

Basic Information
CAS No.: 10028-15-6
Name: Ozone
Molecular Structure:
Molecular Structure of 10028-15-6 (Ozone)
Formula: O3
Molecular Weight: 48.00
Synonyms: Atmosphericozone;Healozone;Oxygen, mol. (O3);Ozone (O3);Ozone(16O16O16O);Triatomicoxygen;
EINECS: 233-069-2
Density: 1.48g/cm3
Melting Point: -192.7℃
Boiling Point: -111.9℃
Flash Point: °C
Solubility:
Appearance: colourless gas or dark blue liquid.
Hazard Symbols: Dangerous fire and explosion risk in contact with organic materials. Toxic by inhalation, strong irritant. TLV: ceiling of 0.1 ppm; STEL 0.3 ppm. EPA standard for ambient air is 0.12 ppm.
Risk Codes:
Safety: A human poison by inhalation. Human systemic effects by inhalation: visual field changes, lachrymation, headache, decreased pulse rate with fall in blood pressure, dermatitis, cough, dyspnea, respiratory stimulation and other pulmonary changes. Experimental teratogenic and reproductive effects. Human mutation data reported. A skin, eye, upper respiratory system, and mucous membrane irritant. Questionable carcinogen with experimental neoplastigenic and tumorigenic data. Can be a safe water disinfectant in low concentration. Concentration of 0.015 ppm of ozone in air produces a barely detectable odor. Concentrations of 1 ppm produce a disagreeable sulfur like odor and may cause headache and irritation of eyes and the upper respiratory tract; symptoms disappear after leaving the exposure.

A powerful oxidizing agent. Dangerous chemical reaction with acetylene, alkenes, alkylmetals (e.g., dimethylzinc, diethylzinc), antimony, aromatic compounds (e.g., benzene, aniline), benzene + oxygen + rubber, bromine, charcoal + potassium iodide, citronellic acid, combustible gases (e.g., carbon monoxide, ethylene, nitrogen oxide, ammonia, phosphine), (diallyl methyl carbinol + acetic acid), trans-2,3-dichloro-2-butene, dicyanogen, dienes + oxygen, diethyl ether, 1,1-difluoroethylene, N2O5, ethylene + formyl fluoride, fluoroethylene, liquid hydrogen, hydrogen + oxygen difluoride, hydrogen bromide, hydrogen iodide, 4-hydroxy-4-methyl-1,6-heptadiene, 2,3-hydroxy-2,2,4-trimethyl-3-pentenoic acid lactone, isopropylidene compounds, nitrogen, NO2, NO, nitrogen trichloride, nitrogen triiodide, nitroglycerin, organic liquids, organic matter, oxygen + rubber powder, oxygen fluorides (e.g., dioxygen difluoride, dioxygen trifluoride), silica gel, stibine, tetrafluorohydrazine, tetramethylammonium hydroxide, trifluoroethylene, unsaturated acetals. A severe explosion hazard in liquid form when shocked, exposed to heat or flame, or in concentrated form by chemical reaction with powerful reducing agents. Incompatible with rubber; dinitrogen tetraoxide. See also OZONIDES and PEROXIDES, INORGANIC; PEROXIDES, ORGANIC.

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Chemistry


IUPAC Name: Ozone
Molecular Formula: O3
Molecular Weight: 47.9982g/mol
Mol File: 10028-15-6.mol
Einecs: 233-069-2
Stability: Unstable - may decompose spontaneously and violently to oxygen. Mixtures containing a moderate partial pressure of ozone, and pure ozone at even low pressures are both potentially explosive. May react very violently with combustible materials and reducing agents, such as organics. Even small quantities of organic material, such as traces of g
Classification Code: Air Pollutants; Environmental Pollutants; Human Data; Mutation data; Noxae; Oxidants; Oxidants, photochemical; Reproductive Effect; Skin / Eye Irritant; Tumor data
Index of Refraction: 1.278 
Molar Refractivity: 5.63 cm3 
Molar Volume: 32.2 cm3
Surface Tension: 47.8 dyne/cm 
Density of Ozone (CAS NO.10028-15-6): 1.48 g/cm

Uses

 Ozone (CAS NO.10028-15-6) is used as a disinfectant for air and water; used for bleaching waxes, textiles and oils, ozonolysis of unsaturated fatty acids to pelargonic and other acids; manufacture of ink; catalyst; water treatment for taste and odor control; mold and bacteria inhibitor in cold storage; bleaching agent. Anti-microbial agents; directly used as a water disinfectant; waste water treatment agent. FDA 2001 Nian 6 Yue apply mutatis mutandis to meat, poultry, raw material handling, storage and processing and preparation of primary agricultural products, packaging and storage.

Production

 Oxygen in the air formed in situ by ultraviolet radiation, or made by air through high-pressure discharge .

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
cat LC50 inhalation 34500ppb/3H (34.5ppm) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
Industrial Medicine and Surgery. Vol. 25, Pg. 301, 1956.
guinea pig LC50 inhalation 24800ppb/3H (24.8ppm) LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES Industrial Medicine and Surgery. Vol. 26, Pg. 63, 1957.
hamster LC50 inhalation 10500ppb/4H (10.5ppm)   AMA Archives of Industrial Health. Vol. 15, Pg. 181, 1957.
human LCLo inhalation 50ppm/30M (50ppm) BEHAVIORAL: HEADACHE

VASCULAR: BP LOWERING NOT CHARACTERIZED IN AUTONOMIC SECTION

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
"Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969Vol. -, Pg. 446, 1969.
human TCLo inhalation 200ppb/4H/4D- (0.2ppm) CARDIAC: PULSE RATE

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
American Journal of Respiratory and Critical Care Medicine. Vol. 161, Pg. 1855, 2000.
human TCLo inhalation 600ppb/2H (0.6ppm) LUNGS, THORAX, OR RESPIRATION: COUGH

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
American Review of Respiratory Disease. Vol. 118, Pg. 287, 1978.
human TCLo inhalation 1ppm (1ppm) LUNGS, THORAX, OR RESPIRATION: COUGH

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Archives of Environmental Health. Vol. 10, Pg. 295, 1965.
human TCLo inhalation 100ppm/1M (100ppm) LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES

SKIN AND APPENDAGES (SKIN): "DERMATITIS, OTHER: AFTER SYSTEMIC EXPOSURE"
News Edition, American Chemical Society. Vol. 19, Pg. 686, 1941.
man TCLo inhalation 80ppb/6.6H (0.08ppm) LUNGS, THORAX, OR RESPIRATION: COUGH

LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
Archives of Environmental Health. Vol. 46, Pg. 145, 1991.
man TCLo inhalation 1860ppb/75M (1.86ppm) SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE

CARDIAC: PULSE RATE

LUNGS, THORAX, OR RESPIRATION: COUGH
Archives of Environmental Health. Vol. 10, Pg. 517, 1965.
mouse LC50 inhalation 12600ppb/3H (12.6ppm) LUNGS, THORAX, OR RESPIRATION: ACUTE PULMONARY EDEMA

BLOOD: HEMORRHAGE
Federation Proceedings, Federation of American Societies for Experimental Biology. Vol. 16, Pg. 22, 1957.
rabbit LC50 inhalation 36ppm/3H (36ppm) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
Industrial Medicine and Surgery. Vol. 25, Pg. 301, 1956.
rat LC50 inhalation 4800ppb/4H (4.8ppm) LUNGS, THORAX, OR RESPIRATION: ACUTE PULMONARY EDEMA

BLOOD: HEMORRHAGE
AMA Archives of Industrial Health. Vol. 15, Pg. 181, 1957.
women TCLo inhalation 350ppb/75M (0.35ppm) LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
Inhalation Toxicology. Vol. 12, Pg. 151, 2000.

Consensus Reports

EPA Extremely Hazardous Substances List. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.

Safety Profile

A human poison by inhalation. Human systemic effects by inhalation: visual field changes, lachrymation, headache, decreased pulse rate with fall in blood pressure, dermatitis, cough, dyspnea, respiratory stimulation and other pulmonary changes. Experimental teratogenic and reproductive effects. Human mutation data reported. A skin, eye, upper respiratory system, and mucous membrane irritant. Questionable carcinogen with experimental neoplastigenic and tumorigenic data. Can be a safe water disinfectant in low concentration. Concentration of 0.015 ppm of ozone in air produces a barely detectable odor. Concentrations of 1 ppm produce a disagreeable sulfur like odor and may cause headache and irritation of eyes and the upper respiratory tract; symptoms disappear after leaving the exposure.
A powerful oxidizing agent. Dangerous chemical reaction with acetylene, alkenes, alkylmetals (e.g., dimethylzinc, diethylzinc), antimony, aromatic compounds (e.g., benzene, aniline), benzene + oxygen + rubber, bromine, charcoal + potassium iodide, citronellic acid, combustible gases (e.g., carbon monoxide, ethylene, nitrogen oxide, ammonia, phosphine), (diallyl methyl carbinol + acetic acid), trans-2,3-dichloro-2-butene, dicyanogen, dienes + oxygen, diethyl ether, 1,1-difluoroethylene, N2O5, ethylene + formyl fluoride, fluoroethylene, liquid hydrogen, hydrogen + oxygen difluoride, hydrogen bromide, hydrogen iodide, 4-hydroxy-4-methyl-1,6-heptadiene, 2,3-hydroxy-2,2,4-trimethyl-3-pentenoic acid lactone, isopropylidene compounds, nitrogen, NO2, NO, nitrogen trichloride, nitrogen triiodide, nitroglycerin, organic liquids, organic matter, oxygen + rubber powder, oxygen fluorides (e.g., dioxygen difluoride, dioxygen trifluoride), silica gel, stibine, tetrafluorohydrazine, tetramethylammonium hydroxide, trifluoroethylene, unsaturated acetals. A severe explosion hazard in liquid form when shocked, exposed to heat or flame, or in concentrated form by chemical reaction with powerful reducing agents. Incompatible with rubber; dinitrogen tetraoxide.
Severe explosion hazard when shocked, exposed to heat or flame, or by chemical reaction with organic substances, especially reducing agents. Ozone is a powerful oxidizing agent. Incompatible with alkenes; aromatic compounds; benzene, rubber; bromine; dicyanogen; diethyl ether; dinitrogen tetroxide; hydrogen bromide; 4-hydroxy-4-methyl-1,6-heptadiene; nitrogen trichloride; stibine; tetrafluorohydrazine. Avoid contact with organic materials.
RIDADR: 1956
HazardClass: 2.2

Standards and Recommendations

OSHA PEL: TWA 0.1 ppm; STEL 0.3 ppm
ACGIH TLV: TWA 0.05 ppm (heavy work), 0.08 ppm (moderate work), 0.10 (light work); all workloads < 2 hours 20 ppm; Not Classifiable as a Human Carcinogen
DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans

Specification

  Ozone (CAS NO.10028-15-6), its Synonyms are Oxygen, mol (O3) ; Ozon ; Ozon [Polish] ; Ozone heavy work ; Triatomic oxygen ; UNII-66H7ZZK23N . It is colourless gas or dark blue liquid and has a characteristic odor in concentrations less than 2 ppm.