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| CAS No.: | 10102-45-1 |
|---|---|
| Name: | THALLIUM(I) NITRATE |
| Molecular Structure: | |
|
|
|
| Formula: | HN O3 . Tl |
| Molecular Weight: | 266.38 |
| Synonyms: | Nitricacid, thallium(1+) salt (8CI,9CI); Thallium nitrate (6CI); Thalliummononitrate; Thallium nitrate (Tl(NO3)); Thallium(1+) nitrate; Thallium(I)nitrate; Thallous nitrate |
| EINECS: | 233-273-1 |
| Density: | g/cm3 |
| Melting Point: |
206 °C(lit.) |
| Boiling Point: | 433 °C |
| Flash Point: | °C |
| Solubility: | g/100g H2O: 3.90 (0°C), 9.55 (20°C), 414 (100°C) [LAN05]; insoluble alcohol [MER06] |
| Appearance: | cubic crystals |
| Hazard Symbols: | A poison. Strong oxidizing agent, fire and explosion risk. TLV: 0.1 mg(Tl)/m3. Toxic by skin absorption. |
| Risk Codes: | 26/28-33-51/53 |
| Safety: | Poison by ingestion, intravenous, intraperitoneal, and subcutaneous routes. Human systemic effects by ingestion: hypermotility, diarrhea, nausea or vomiting, and dehydration. Mutation data reported. When heated to decomposition it emits very toxic fumes of Tl and NOx. See also THALLIUM COMPOUNDS and NITRATES. |
| PSA: | 68.88000 |
| LogP: | 0.28410 |
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Chemistry
IUPAC Name: Thallium(1+) nitrate
Synonyms: Nitric acid, thallium(1+) salt ;Nitricacid,thallium(1+)salt ; Nitricacid,thallium(1++)salt ; Rcra waste number U217 ; Rcrawastenumberu217 ; Thallium mononitrate ; Thallium nitrate (Tl(NO3)) ; Thallium(I) nitrate (1:1)
Product Categories: Micro/Nanoelectronics;Solution Deposition Precursors;Thallium;Metal and Ceramic Science;Salts;Thallium Salts
CAS: 10102-45-1
Molecular Formula: NO3Tl
Molecular Weight:266.39
Molecular Struture: 
EINECS: 233-273-1
Mol File: 10102-45-1.mol
Enthalpy of Vaporization: 37.72 kJ/mol
Boiling Point: 83 °C at 760 mmHg
Vapour Pressure: 49.8 mmHg at 25°C
Appearance:cubic crystals
Melting point: 206 °C(lit.)
Boiling point: 433 °C
Density: 5,55 g/cm3
Merck : 14,9265
Stability: Thallium nitrate (10102-45-1) Stable. Strong oxidizing agent.
Uses
Thallium nitrate (10102-45-1) is used for quantitative analysis of co-existence of chlorine, bromine, iodine,which is also used as optical fiber materials.
Toxicity Data With Reference
| 1. | mrc-bcs 1 mmol/L | MUREAV Mutation Research. 77 (1980),109. | ||
| 2. | orl-man TDLo:73 mg/kg:GIT,MET | SMEZA5 Sudebno-Meditsinskaya Ekspertiza. Forensic Medical Examination. 18 (4)(1975),37. | ||
| 3. | ipr-rat LD50:21 µg/kg | AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. 182 (1969),425. | ||
| 4. | scu-rat LD50:26 mg/kg | 85ECAN Metal Toxicity in Mammals, Vol. 2: Chemical Toxicity of Metals and Metalloids. 2 (1978),101. | ||
| 5. | orl-mus LD50:15 mg/kg | YKYUA6 Yakkyoku. Pharmacy. 28 (1977),329. | ||
| 6. | ipr-mus LD50:37,293 µg/kg | TXAPA9 Toxicology and Applied Pharmacology. 63 (1982),461. | ||
| 7. | orl-dog LDLo:45 mg/kg | HBAMAK “Abdernalden’s Handbuch der Biologischen Arbeitsmethoden.“ 4 (1935),1406. | ||
| 8. | scu-dog LDLo:15 mg/kg | EQSSDX Environmental Quality and Safety, Supplement. 1 (1975),1. | ||
| 9. | ivn-dog LDLo:15 mg/kg | EQSSDX Environmental Quality and Safety, Supplement. 1 (1975),1. | ||
| 10. | ivn-rbt LDLo:14 mg/kg | EQSSDX Environmental Quality and Safety, |
Consensus Reports
Thallium and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.
Safety Profile
Hazard Codes T+.gif){kind=small}
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Risk Statements 26/28-33-51/53
33: Danger of cumulative effects
26/28: Thallium nitrate (10102-45-1) is very Toxic by inhalation and if swallowed
51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Safety Statements 13-28-45-61
28: After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer)
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
13: Keep away from food, drink and animal feeding stuffs
61: Avoid release to the environment. Refer to special instructions safety data sheet
RIDADR UN 2727 6.1/PG 2
WGK Germany 2
RTECS XG5950000
HazardClass 6.1
PackingGroup II
Standards and Recommendations
OSHA PEL: TWA 0.1 mg(Tl)/m3 (skin)
ACGIH TLV: TWA 0.1 mg(Tl)/m3 (skin)
DOT Classification: 6.1; Label: Poison, Oxidizer
Specification
1.General Description: A colorless crystalline solid melting at 206°C. Toxic by ingestion and skin absorption. Used to make other chemicals.
2.Air & Water Reactions: Water soluble.
3.Reactivity Profile :Thallium nitrate (10102-45-1) is an oxidizing agent. May start a fire when in contact with organic materials. Mixtures with alkyl esters may explode, owing to the formation of alkyl nitrates. Mixtures with phosphorus, tin(II) chloride, or other reducing agents may react explosively
4.Health Hazard Thallium is one of the more toxic elements both as an acute and a chronic poison. Effects of exposure are cumulative and onset of symptoms may be delayed 12 to 24 hours. May be fatal if inhaled, ingested or absorbed through the skin. Irritating to skin and eyes. Readily absorbed through the skin and digestive tract. Ingestion of soluble thallium compounds has caused many deaths Ingestion of sublethal quantities may cause nausea, vomiting, diarhea, abdominal pain, and bleeding from the gut accompanied or followed by drooping eyelids, crossed eyes, weakness, numbness, tingling of arms and legs, trembling, tightness and pain in the chest. Loss of hair may occur in two to three weeks. Severe intoxication may cause prostration, rapid heartbeat, convulsions, and psychosis. Some effects may be permanent.