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102-08-9

Basic Information
CAS No.: 102-08-9
Name: 1,3-Diphenyl-2-thiourea
Article Data: 207
Cas Database
Molecular Structure:
Molecular Structure of 102-08-9 (1,3-Diphenyl-2-thiourea)
Formula: C13H12N2S
Molecular Weight: 228.318
Synonyms: Carbanilide,thio- (6CI,7CI,8CI);1,3-Diphenyl-2-thiourea;1,3-Diphenylthiourea;AccelerantCA;Diphenylthiourea;N,N'-Diphenylthiocarbamide;N,N'-Diphenylthiourea;NSC28134;NSC 686;Nocceler C;Rhenocure CA;Stabilisator C;Sulfocarbanilide;Thiocarbanilide;Vulkacit CA;s-Diphenylthiocarbamide;sym-Diphenylthiourea;
EINECS: 203-004-2
Density: 1.284 g/cm3
Melting Point: 152-155 °C(lit.)
Boiling Point: 348.7 °C at 760 mmHg
Flash Point: 164.7 °C
Solubility: <0.01 g/100 mL at 19 °C in water
Appearance: white powder
Hazard Symbols: ToxicT
Risk Codes: 25
Safety: 36/37/39-45-24/25
Transport Information: UN 2811 6.1/PG 2
PSA: 56.15000
LogP: 3.64150
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Chemistry

Molecular Formula: C13H12N2S
Molecular Weight: 228.33
EINECS: 203-004-2
Density: 1.284 g/cm3
Melting Point: 151-154 °C
Boiling Point: 50 °C
Flash Point: 164.7 °C
Solubility: <0.01 g/100 mL at 19 °C
Appearance: White powder
Structure of Thiocarbanilide (CAS NO.102-08-9): 
                 
IUPAC Name: 1,3-Diphenylthiourea

Uses

 Thiocarbanilide (CAS NO.102-08-9) can be used for determination reagent of osmium and ruthenium, sulfur slurry accelerator, and is also used in dye industry.

Toxicity Data With Reference

1.    

orl-rat LD50:50 mg/kg

    ARTODN    Archives of Toxicology. 54 (1983),275.
2.    

ipr-rat LD50:1000 mg/kg

    MEPAAX    Medycyna Pracy. Industrial Medicine. 16 (1965),35.
3.    

ipr-mus LD50:500 mg/kg

    NTIS**    National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) AD277-689 .
4.    

orl-cat LDLo:720 mg/kg

    JPETAB    Journal of Pharmacology and Experimental Therapeutics. 17 (1921),349.
5.    

orl-rbt LDLo:1500 mg/kg

    MEIEDD    Merck Index. 10 (1983),487.

 Thiocarbanilide (CAS NO.102-08-9) hasn't been listed as a carcinogen by NTP, IARC, ACGIH, or CA Prop 65. You can see actual entry in RTECS for complete information.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Moderately toxic by ingestion and intraperitoneal routes. Experimental reproductive effects. When heated to decomposition it emits highly toxic fumes of SOx and NOx.
Hazard Codes: ToxicT
Risk Statements: 25 
R25 :Toxic if swallowed.
Safety Statements: 36/37/39-45-24/25 
S24/25:Avoid contact with skin and eyes. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)

Specification

 Thiocarbanilide , its cas register number is 102-08-9. It also can be called N,N'-Diphenylthiourea ; sym-Diphenylthiourea ; and 1,3-Diphenyl-2-thiourea . It is hazardous, so the first aid measures and others should be known. Such as: When on the skin: first, should flush skin with plenty of water immediately for at least 15 minutes while removing contaminated clothing. Secondly, get medical aid. Or in the eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Then get medical aid soon. While, it's inhaled: Remove from exposure and move to fresh air immediately. Then you have the ingesting of the product: If victim is conscious and alert, give 2-4 cupfuls of milk or water. In addition, Thiocarbanilide (CAS NO.102-08-9) could be stable under normal temperatures and pressures. And also prevent it to broken down into hazardous decomposition products: nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide, nitrogen.