102-70-5

The Triallylamine with CAS registry number of 102-70-5 is also called 2-Propen-1-amine,N,N-di-2-propen-1-yl-. The IUPAC name is N,N-bis(prop-2-enyl)prop-2-en-1-amine. Its EINECS registry number is 203-048-2. In addition, the molecular formula is C₉H₁₅N and the molecular weight is 137.22. It is a kind of dark brown liquid and belongs to the classes of Acyclic; Alkenes; Organic Building Blocks. And tt should be stored in a cool and ventilated place.

Physical properties about this chemical are: (1)ACD/LogP: 3.32 ; (2)ACD/LogD (pH 5.5): 1.69; (3)ACD/LogD (pH 7.4): 3.13; (4)ACD/BCF (pH 5.5): 4.61; (5)ACD/BCF (pH 7.4): 127.74; (6)ACD/KOC (pH 5.5): 35.71; (7)ACD/KOC (pH 7.4): 990.08; (8)#H bond acceptors: 1; (9)#Freely Rotating Bonds: 6; (10)Polar Surface Area: 3.24 Å²; (11)Index of Refraction: 1.462; (12)Molar Refractivity: 46.64 cm³; (13)Molar Volume: 169.6 cm³; (14)Polarizability: 18.49 ×10^-24cm³; (15)Surface Tension: 25.9 dyne/cm; (16)Density: 0.808 g/cm³; (17)Flash Point: 30.6 °C; (18)Enthalpy of Vaporization: 39.43 kJ/mol; (19)Boiling Point: 157.6 °C at 760 mmHg; (20)Vapour Pressure: 2.74 mmHg at 25°C.

Preparation of Triallylamine: it can be prepared by diallylamine and 3-acetoxy-propene. This reaction will need reagent cis,cis,cis-1,2,3,4-tetrakis(Ph₂PCH₂)cyclopentane, catalyst [PdCl(C₃H₅)]₂ and solvent tetrahydrofuran. The reaction time is 130 hours at reaction temperature of 25 °C. The yield is about 95%.

Uses of Triallylamine: this chemical is used as extractant of uranium and rare metals, and it can be used for organic synthesis and resin modified. In addition, it can be used as intermediate of ion exchange resins, crosslinker of high absorbent and metal resist. What's more, it can react with 4-ethyl-aniline to get 2,6-diethyl-3-methyl-quinoline. This reaction will need reagents ruthenium(III) chloride hydrate, bis(diphenylphosphino)methane and tin(II) chloride dihydrate, and solvent dioxane. The reaction time is 20 hours at reaction temperature of 180 °C. The yield is about 65%.

When you are using this chemical, please be cautious about it as the following:
This chemical is flammable and can cause burns. And it is harmful by inhalation, in contact with skin and if swallowed. During using it, wear suitable protective clothing, gloves and eye/face protection. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. And in case of accident or if you feel unwell, seek medical advice immediately (show label where possible). What's more, you should keep away from sources of ignition.

You can still convert the following datas into molecular structure:
(1)SMILES: C(=C)\CN(C\C=C)C\C=C
(2)InChI: InChI=1/C9H15N/c1-4-7-10(8-5-2)9-6-3/h4-6H,1-3,7-9H2
(3)InChIKey: VPYJNCGUESNPMV-UHFFFAOYAI

The toxicity data is as follows: