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Basic Information
CAS No.: 10347-38-3
Name: Thiobis(tribenzylstannane)
Molecular Structure:
Molecular Structure of 10347-38-3 (Thiobis(tribenzylstannane))
Formula: C42H42 S Sn2
Molecular Weight: 816.281
Synonyms: Distannathiane,hexakis(phenylmethyl)- (9CI); Tin, thiobis[tribenzyl- (7CI,8CI);Bis(tribenzylstannyl) sulfide; Bis(tribenzyltin) sulfide
Density: g/cm3
Boiling Point: °Cat760mmHg
Flash Point: °C
Hazard Symbols: A poison by ingestion. A skin and eye irritant. TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin).
Safety: Poison by ingestion. A skin and eye irritant. See also TIN COMPOUNDS and SULFIDES. When heated to decomposition it emits toxic fumes of SOx.

Analytical Methods:

   

For occupational chemical analysis use NIOSH: Organotin Compounds 5504.

PSA: 25.30000
LogP: 9.51780
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Chemistry

IUPAC Name: : Tribenzyl(tribenzylstannylsulfanyl)stannane
Synonyms of Bis(tribenzylstannium) sulfide (CAS NO.10347-38-3): Bis(tribenzyltin) sulfide ; Hexakis(phenylmethyl)distannathiane ; Sirnik tribenzylcinicity ; Thiobis(tribenzyltin) ; Distannathiane, hexakis(phenylmethyl)- (9CI) ; Sulfide, bis(tribenzylstannyl) ; Tin, thiobis(tribenzyl- (8CI)
InChI: InChI=1/6C7H7.S.2Sn/c6*1-7-5-3-2-4-6-7;;;/h6*2-6H,1H2;;;/rC42H42SSn2/c1-7-19-37(20-8-1)31-44(32-38-21-9-2-10-22-38,33-39-23-11-3-12-24-39)43-45(34-40-25-13-4-14-26-40,35-41-27-15-5-16-28-41)36-42-29-17-6-18-30-42/h1-30H,31-36H2
InChIKey: RLKWXZLMMDRNDU-QYZUWZJHAC
Std. InChI: InChI=1S/6C7H7.S.2Sn/c6*1-7-5-3-2-4-6-7;;;/h6*2-6H,1H2;;;
Std. InChIKey: RLKWXZLMMDRNDU-UHFFFAOYSA-N
CAS NO: 10347-38-3
Molecular Formula: C42H42SSn2
Molecular Weight: 816.2679
Molecular Structure :
H bond acceptors: 0
H bond donors: 0
Freely Rotating Bonds: 14
Polar Surface Area: 25.3 Å2
Flash Point: 412.5 °C
Enthalpy of Vaporization: 106.6 kJ/mol
Boiling Point: 758.5 °C at 760 mmHg
Vapour Pressure: 5.49E-22 mmHg at 25°C

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rat LD50 oral 314mg/kg (314mg/kg)   "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986Vol. -, Pg. 1256, 1986.

Safety Profile

Poison by ingestion. A skin and eye irritant. See also TIN COMPOUNDS and SULFIDES. When Bis(tribenzylstannium) sulfide (CAS NO.10347-38-3) is heated to decomposition ,it emits toxic fumes of SOx.

Standards and Recommendations

OSHA PEL: TWA 0.1 mg(Sn)/m3 (skin)
ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL 0.2 mg(Sn)/m3 (skin).
NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m3

Analytical Methods

For occupational chemical analysis use NIOSH: Organotin Compounds 5504.