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| CAS No.: | 108549-23-1 |
|---|---|
| Name: | DIBENZYL DIISOPROPYLPHOSPHORAMIDITE |
| Molecular Structure: | |
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| Formula: | C20H28NO2P |
| Molecular Weight: | 345.422 |
| Synonyms: | Phosphoramidousacid, bis(1-methylethyl)-, bis(phenylmethyl) ester (9CI);Bis(benzyloxy)(diisopropylamino)phosphine;Dibenzyl diisopropylphosphoramidite;dibenzyl dipropan-2-ylphosphoramidoite;Phosphoramidous acid, bis(1-methylethyl)-, bis(phenylmethyl) ester;phosphoramidous acid, N,N-bis(1-methylethyl)-, bis(phenylmethyl) ester;bis(benzyloxy)(diisopropylamino)phosphine;Dibenzyl-N,N-disisopropylphosphoramidite; |
| EINECS: | 629-628-9 |
| Density: | 1.028g/mLat 25°C(lit.) |
| Boiling Point: | 382 °C at 760 mmHg |
| Flash Point: | 184.8 °C |
| Appearance: | Clear colourless liquid |
| Hazard Symbols: |
 Xi
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| Risk Codes: | 36/37/38 |
| Safety: | 26-36-37/39 |
| PSA: | 35.29000 |
| LogP: | 5.76570 |
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Specification
The Bis-bzl-2iPr-P, with the CAS registry number 108549-23-1, has the systematic name of dibenzyl dipropan-2-ylphosphoramidoite. It is a kind of clear colourless liquid, and belongs to the following product categories: Phospholipids - 13C & 2H; Biochemistry; Nucleosides, Nucleotides & Related Reagents; Phosphorylating and Phosphorothioating Agents; Phosphorylation; Protecting Agents, Phosphorylating Agents & Condensing Agents; Synthetic Organic Chemistry; Phosphorylating and Phosphitylating Agents; Organic Building Blocks; Phosphoramidites; Phosphorus Compounds. And the molecular formula of the chemical is C20H28NO2P.
The characteristics of Bis-bzl-2iPr-P are as followings: (1)ACD/LogP: 6.82; (2)# of Rule of 5 Violations: 1 ; (3)#H bond acceptors: 3; (4)#H bond donors: 0; (5)#Freely Rotating Bonds: 9; (6)Polar Surface Area: 35.29 Å2; (7)Flash Point: 184.8 °C; (8)Enthalpy of Vaporization: 63.03 kJ/mol; (9)Boiling Point: 382 °C at 760 mmHg; (10)Vapour Pressure: 4.88E-06 mmHg at 25°C.
Preparation of Bis-bzl-2iPr-P: This chemical can be prepared by phenylmethanol and dichloro(diisopropylamino)phosphine. The reaction will need reagent Et3N, and the menstruum tetrahydrofuran. The reaction time is 2 hours with ambient temperature, and the yield is about 72%.
You should be cautious while dealing with this chemical. It irritates to eyes, respiratory system and skin. Therefore, you had better take the following instructions: Wear suitable protective clothing, and if in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice.
Addtionally, the following datas could be converted into the molecular structure:
(1)SMILES: O(P(OCc1ccccc1)N(C(C)C)C(C)C)Cc2ccccc2
(2InChI: InChI=1/C20H28NO2P/c1-17(2)21(18(3)4)24(22-15-19-11-7-5-8-12-19)23-16-20-13-9-6-10-14-20/h5-14,17-18H,15-16H2,1-4H3
(3)InChIKey: ANPWLBTUUNFQIO-UHFFFAOYAA