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| CAS No.: | 110-68-9 |
|---|---|
| Name: | N-METHYLBUTYLAMINE |
| Molecular Structure: | |
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|
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| Formula: | C5H13 N |
| Molecular Weight: | 87.1649 |
| Synonyms: | Butylamine,N-methyl- (6CI,7CI,8CI); Butylmethylamine; Methylaminobutane; Methylbutylamine;N-Butyl-N-methylamine; N-Butylmethylamine; N-Methyl-1-butanamine;N-Methyl-n-butylamine; N-Methylbutanamine; N-Methylbutylamine |
| Density: | 0.736 |
| Melting Point: | -75 °C |
| Boiling Point: |
90.5-91.5 °C(lit.) |
| Flash Point: | 1.7°C |
| Appearance: | CLEAR COLOURLESS LIQUID |
| Hazard Symbols: | Flammable, dangerous fire risk. |
| Risk Codes: | 11-20/21/22-34 |
| Safety: | Poison by intravenous route. Moderately toxic by ingestion, skin contact, and intraperitoneal routes. Mildly toxic by inhalation. A skin and severe eye irritant. Flammable liquid when exposed to heat, sparks, or flame. To fight fire, use alcohol foam. When heated to decomposition it emits toxic fumes of NOx. See also AMINES. |
| PSA: | 12.03000 |
| LogP: | 1.39680 |
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Chemistry
Product Name: n-Methyl-n-butylamine (110-68-9)
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Molecular Formula: C5H13N
Molecular Weight: 87.16g/mol
Mol File: 110-68-9.mol
Einecs: 203-791-2
Appearance: clear colourless liquid
Melting Point: -75 °C
Boiling point: 91.5 °C at 760 mmHg
Storage Temperature: Flammables area
Flash Point: 1.7 °C
Density: 0.736 g/mL at 25 °C(lit.)
Refractive index: n20/D 1.3995(lit.)
Synonyms of n-Methyl-n-butylamine (110-68-9): 1-Butanamine,N-methyl- ; Butylamine, N-methyl- ; Butylamine,N-methyl- ; Butylmethylamine ; Methylaminobutane ; Methylbutylamine ; Methyl-N-butylamine ; N-Butylmethylamin .
Toxicity Data With Reference
May cause toxic effects if inhaled or ingested/swallowed. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| mouse | LD50 | intraperitoneal | 471mg/kg (471mg/kg) | Journal of Pharmacology and Experimental Therapeutics. Vol. 88, Pg. 82, 1946. | |
| mouse | LD50 | intravenous | 122mg/kg (122mg/kg) | Journal of Pharmacology and Experimental Therapeutics. Vol. 88, Pg. 82, 1946. | |
| rabbit | LD50 | skin | 1260uL/kg (1.26mL/kg) | SKIN AND APPENDAGES (SKIN): PRIMARY IRRITATION: AFTER TOPICAL EXPOSURE | American Industrial Hygiene Association Journal. Vol. 23, Pg. 95, 1962. |
| rat | LCLo | inhalation | 2000ppm/4H (2000ppm) | Union Carbide Data Sheet. Vol. 7/6/1970, | |
| rat | LD50 | oral | 420mg/kg (420mg/kg) | Union Carbide Data Sheet. Vol. 7/6/1970, |
Consensus Reports
Reported in EPA TSCA Inventory.
Safety Profile
Poison by intravenous route. Moderately toxic by ingestion, skin contact, and intraperitoneal routes. Mildly toxic by inhalation. A skin and severe eye irritant. Flammable liquid when exposed to heat, sparks, or flame. To fight fire, use alcohol foam. When heated to decomposition it emits toxic fumes of NOx. See also AMINES.
Flammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
Safety Information of n-Methyl-n-butylamine (110-68-9):
Hazard Codes: F.gif){kind=small}
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Risk Statements: 11-20/21/22-34
11: Highly Flammable
20: Harmful by inhalation
21: Harmful in contact with skin
22: Harmful if swallowed
34: Causes burns
Safety Statements: 16-26-36/37/39-45
16: Keep away from sources of ignition - No smoking
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36: Wear suitable protective clothing
37: Wear suitable gloves
39: Wear eye/face protection
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
Standards and Recommendations
DOT Classification: 3; Label: Flammable Liquid
Specification
A water-white liquid with an ammonia-like odor. Density 0.736 g / cm3 and flash point 35°F (Aldrich) .Vapors heavier than air. Used to make other chemicals.