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110-68-9

Basic Information
CAS No.: 110-68-9
Name: N-METHYLBUTYLAMINE
Article Data: 66
Molecular Structure:
Molecular Structure of 110-68-9 (N-METHYLBUTYLAMINE)
Formula: C5H13 N
Molecular Weight: 87.1649
Synonyms: Butylamine,N-methyl- (6CI,7CI,8CI); Butylmethylamine; Methylaminobutane; Methylbutylamine;N-Butyl-N-methylamine; N-Butylmethylamine; N-Methyl-1-butanamine;N-Methyl-n-butylamine; N-Methylbutanamine; N-Methylbutylamine
Density: 0.736
Melting Point: -75 °C
Boiling Point: 90.5-91.5 °C(lit.)
Flash Point: 1.7°C
Appearance: CLEAR COLOURLESS LIQUID
Hazard Symbols: Flammable, dangerous fire risk.
Risk Codes: 11-20/21/22-34
Safety: Poison by intravenous route. Moderately toxic by ingestion, skin contact, and intraperitoneal routes. Mildly toxic by inhalation. A skin and severe eye irritant. Flammable liquid when exposed to heat, sparks, or flame. To fight fire, use alcohol foam. When heated to decomposition it emits toxic fumes of NOx. See also AMINES.
PSA: 12.03000
LogP: 1.39680
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  • 110-68-9               C5H13N                    N-METHYLBUTYLAMINE

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Chemistry

Product Name: n-Methyl-n-butylamine (110-68-9)


Molecular Formula: C5H13N
Molecular Weight: 87.16g/mol
Mol File: 110-68-9.mol
Einecs: 203-791-2
Appearance: clear colourless liquid
Melting Point: -75 °C
Boiling point: 91.5 °C at 760 mmHg
Storage Temperature: Flammables area
Flash Point: 1.7 °C
Density: 0.736 g/mL at 25 °C(lit.)
Refractive index: n20/D 1.3995(lit.)
Synonyms of  n-Methyl-n-butylamine (110-68-9): 1-Butanamine,N-methyl- ; Butylamine, N-methyl- ; Butylamine,N-methyl- ; Butylmethylamine ; Methylaminobutane ; Methylbutylamine ; Methyl-N-butylamine ; N-Butylmethylamin .

Toxicity Data With Reference

May cause toxic effects if inhaled or ingested/swallowed. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 471mg/kg (471mg/kg)   Journal of Pharmacology and Experimental Therapeutics. Vol. 88, Pg. 82, 1946.
mouse LD50 intravenous 122mg/kg (122mg/kg)   Journal of Pharmacology and Experimental Therapeutics. Vol. 88, Pg. 82, 1946.
rabbit LD50 skin 1260uL/kg (1.26mL/kg) SKIN AND APPENDAGES (SKIN): PRIMARY IRRITATION: AFTER TOPICAL EXPOSURE American Industrial Hygiene Association Journal. Vol. 23, Pg. 95, 1962.
rat LCLo inhalation 2000ppm/4H (2000ppm)   Union Carbide Data Sheet. Vol. 7/6/1970,
rat LD50 oral 420mg/kg (420mg/kg)   Union Carbide Data Sheet. Vol. 7/6/1970,

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by intravenous route. Moderately toxic by ingestion, skin contact, and intraperitoneal routes. Mildly toxic by inhalation. A skin and severe eye irritant. Flammable liquid when exposed to heat, sparks, or flame. To fight fire, use alcohol foam. When heated to decomposition it emits toxic fumes of NOx. See also AMINES.
Flammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
Safety Information of n-Methyl-n-butylamine (110-68-9):
Hazard Codes: F,C
Risk Statements: 11-20/21/22-34 
11:  Highly Flammable
20:  Harmful by inhalation 
21:  Harmful in contact with skin 
22:  Harmful if swallowed 
34:  Causes burns
Safety Statements: 16-26-36/37/39-45
16:  Keep away from sources of ignition - No smoking
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36:  Wear suitable protective clothing  
37:  Wear suitable gloves   
39:  Wear eye/face protection 
45:  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)

Standards and Recommendations

DOT Classification:  3; Label: Flammable Liquid

Specification

A water-white liquid with an ammonia-like odor. Density 0.736 g / cm3 and flash point 35°F (Aldrich) .Vapors heavier than air. Used to make other chemicals.