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111-84-2

Basic Information
CAS No.: 111-84-2
Name: n-Nonane
Article Data: 206
Molecular Structure:
Molecular Structure of 111-84-2 (n-Nonane)
Formula: C9H20
Molecular Weight: 128.258
Synonyms: n-Nonane;NSC 72430;Shellsol 140;
EINECS: 203-913-4
Density: 0.724 g/cm3
Melting Point: -53 °C
Boiling Point: 151.7 °C at 760 mmHg
Flash Point: 31.1 °C
Solubility: Immiscible with water
Appearance: colorless liquid
Hazard Symbols: HarmfulXn
Risk Codes: 10-67-65-53-20
Safety: 62-24/25-23
Transport Information: UN 1920 3/PG 3
PSA: 0.00000
LogP: 3.75690
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Chemistry

Molecular Formula: C9H20
Formula Weight: 128.26
mp : -53 °C
bp : 151 °C(lit.)
Fp : 88 °F
density : 0.72 g/mL at 20 °C
vapor density : 4.41 (vs air)
vapor pressure : 0.18 psi ( 37.7 °C)
refractive index : n20/D 1.407
storage temp. : Flammables area
Physical state and appearance: Liquid.
Odor of NONANE: Gasoline-like odor
Stability: NONANE is stable.

Toxicity Data With Reference

1.   

ihl-rat LC50:3200 ppm/4H

   TXAPA9    Toxicology and Applied Pharmacology. 44 (1978),53.
2.   

ivn-mus LD50:218 mg/kg

   JPMSAE    Journal of Pharmaceutical Sciences. 67 (1978),566.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Xn N - Harmful, Dangerous for the environment.
R 10 - Flammable.
R 20 - Harmful by inhalation.
R 53 - May cause long-term adverse effects in the aquatic wnvironment.
R 65 - Harmful: may cause lung damage if swallowed.
R 67 - Vapours may cause frowsiness and dizziness.
S 02 - Keep out of the reach of children.
S 16 - Keep away from sources of ignition - No Smoking.
S 23 - Do not breath vapour.
S 24/25 - Avoid contact with skin and eyes.
S 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 37/39 - Wear suitable gloves and eye/face protection.
S 61 - Avoid release to the environment. Refer to special instructions/safety data sheet.
S 62 - If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
RIDADR : UN 1920 3/PG 3
WGK Germany : 3
RTECS : RA6115000
HazardClass : 3
PackingGroup : III 
Poison by intravenous route. Mildly toxic by inhalation. Irritating to respiratory tract. Narcotic in high concentrations. A very dangerous fire hazard when exposed to heat or flame; can react with oxidizing materials. Explosive in the form of vapor when exposed to heat or flame. Emitted from modern building materials ( CENEAR    Chemical and Engineering News. 69 (1991),22. ). To fight fire, use CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.

Standards and Recommendations

OSHA PEL: TWA 200 ppm
ACGIH TLV: TWA 200 ppm
DOT Classification:  3; Label: Flammable Liquid

Specification

Storage of NONANE: Keep in a cool, well-ventilated place. Keep away from sources of ignition. Keep container tightly closed. Keep away from heat. Flammable materials should be stored in a separate safety storage cabinet or room. Ground all equipment containing material. A refrigerated room would be preferable for materials with a flash point lower than 37.8°C (100°F).