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1117-94-8

Basic Information
CAS No.: 1117-94-8
Name: COPPER(I)ACETYLIDE
Article Data: 2
Molecular Structure:
Molecular Structure of 1117-94-8 (COPPER(I)ACETYLIDE)
Formula: C2Cu2
Molecular Weight: 151.114
Synonyms: Copperacetylene; Copper acetylide (Cu2C2); Ethyne, dicopper(1+) deriv.
Melting Point: explodes [CRC10]
Solubility: very slightly soluble H2O [CRC10]
Hazard Symbols: TLV: (fume) 0.2 mg/m3; (dust, mist) 1 mg(Cu)/m3; (Proposed: (fume and respirable particles) 0.05 mg/m3; (dust, mist) 1 mg(Cu)/m3). Explodes on impact or heating to 100°C.
Safety: An unstable material. It explodes on impact or heating to 100°C. If warmed in air or oxygen it explodes on subsequent contact with acetylene. The sensitivity of the acetylide when precipitated from solution increases with acidity of the solution. It ignites on contact with chlorine; bromine vapor; or finely divided iodine. Reaction with silver nitrate solutions produces a sensitive, explosive mixture of silver acetylide and silver. When heated to decomposition it emits acrid smoke and fumes. See also COPPER COMPOUNDS and ACETYLIDES.
PSA: 0.00000
LogP: -0.00160
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Consensus Reports

COPPER and its compounds are on the Community Right-To-Know List.

Safety Profile

An unstable material. It explodes on impact or heating to 100°C. If warmed in air or OXYGEN it explodes on subsequent contact with acetylene. The sensitivity of the acetylide when precipitated from solution increases with acidity of the solution. It ignites on contact with chlorine; bromine vapor; or finely divided iodine. Reaction with SILVER nitrate solutions produces a sensitive, explosive mixture of SILVER acetylide and SILVER. When heated to decomposition it emits acrid smoke and fumes. See also COPPER COMPOUNDS and ACETYLIDES.

Standards and Recommendations

ACGIH TLV: TWA (fume) 0.2 mg/m3; (dust, mist) 1 mg(Cu)/m3