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| CAS No.: | 1122-60-7 |
|---|---|
| Name: | NITROCYCLOHEXANE |
| Article Data: | 120 |
| Molecular Structure: | |
|
|
|
| Formula: | C6H11 N O2 |
| Molecular Weight: | 129.159 |
| Synonyms: | NSC 66277;Nitrocyclohexane |
| Density: | 1.05g/cm3 |
| Melting Point: |
−34 °C(lit.) |
| Boiling Point: |
205.5-206 °C768 mm Hg(lit.) |
| Flash Point: | 81.2°C |
| Hazard Symbols: |
|
| Risk Codes: | 23/24/25-36/37/38 |
| Safety: | Poison by ingestion and inhalation. When heated to decomposition it emits toxic fumes of NOx. See also NITRO COMPOUNDS. |
| PSA: | 45.82000 |
| LogP: | 2.11900 |
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Chemistry
Chemistry informtion about Nitrocyclohexane (CAS NO.1122-60-7) is:
IUPAC Name: Nitrocyclohexane
Synonyms: Ai3-14828[Qr] ; Cyclohexane,Nitro-[Qr] ; Nitro-Cyclohexan ; Nitrocyclohexane ; Hexahydronitrobenzene ; Nitrocyclohexane ,97% ; 1-Nitrocyclohexanev
MF: C6H11NO2
MW: 129.16
EINECS: 214-354-0
Density: 1.05 g/cm3
Melting Point: −34 °C(lit.)
Flash Point: 81.2 °C
Boiling Point: 202.8 °C at 760 mmHg
Vapour Pressure: 0.287 mmHg at 25°C
Enthalpy of Vaporization: 43.9 kJ/mol
Refractive index: n20/D 1.462(lit.)
Following is the molecular structure of Nitrocyclohexane (CAS NO.1122-60-7) is:
Production
Raw materials: 3-Chloroperoxybenzoic acid-->1,2-Dichloroethane -->Cyclohexylamine
Preparation Products: Cyclohexylamine-->3-Amino-2-azepanone
Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| mouse | LCLo | inhalation | 7mg/m3/2H (7mg/m3) | behavioral: somnolence (general depressed activity) behavioral: excitement behavioral: muscle contraction or spasticity) | Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. Vol. 1, Pg. 85, 1961. |
| mouse | LDLo | oral | 120mg/kg (120mg/kg) | Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. Vol. 1, Pg. 85, 1961. | |
| rabbit | LDLo | oral | 100mg/kg (100mg/kg) | behavioral: convulsions or effect on seizure threshold | Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 26(5), Pg. 9, 1961. |
| rat | LCLo | inhalation | 172ppm/4H (172ppm) | sense organs and special senses: other: eye gastrointestinal: "hypermotility, diarrhea" | National Technical Information Service. Vol. OTS0590060, |
| rat | LDLo | oral | 100mg/kg (100mg/kg) | behavioral: convulsions or effect on seizure threshold | Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 26(5), Pg. 9, 1961. |
Consensus Reports
EPA Extremely Hazardous Substances List.
Safety Profile
Poison by ingestion and inhalation. When heated to decomposition it emits toxic fumes of NOx. See also NITRO COMPOUNDS.
Hazard Codes:
T
Risk Statements:
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements:
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR: UN 3382 6.1/PG 1
WGK Germany: 3
RTECS: GV6600000
HazardClass: 6.1(b)
PackingGroup: III
Specification
General Description about Nitrocyclohexane (CAS NO.1122-60-7) , it is a colorless liquid. It highly flammable with water.Also, it range from slight to strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. Nitroalkanes are milder oxidizing agents, but still react violently with reducing agents at higher temperature and pressures. Nitroalkanes react with inorganic bases to form explosive salts. The presence of metal oxides increases the thermal sensitivity of nitroalkanes. Nitroalkanes with more than one nitro group are generally explosive. Nitroalkanes are insoluble in water. Flammable/combustible material. May be ignited by heat, sparks or flames.