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12002-03-8

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Basic Information
CAS No.: 12002-03-8
Name: Copper acetoarsenite
Molecular Structure:
Molecular Structure of 12002-03-8 (Copper acetoarsenite)
Formula: Cu(C2H3O2)2·3Cu(AsO2)2
Molecular Weight: 1013.78
Synonyms: BasleGreen;C.I. 77410;Cupric acetoarsenite;Genuine Paris Green;Imperial Green;Mineral Green;Mitis green;Mountain Green;Neuwied Green;New Green;Parisgreen;Powder Green;Schweinfurt green;Swedish Green;ViennaGreen;Wuerzberg Green;Zwickau Green;
Density: >1.1(20oC)
Solubility: insoluble H2O, decomposed by prolonged heating; unstable in acids [MER06]
PSA: 293.38000
LogP: -3.01780
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Chemistry

Product Name: Copper acetoarsenite
CAS: 12002-03-8
The Molecular formula of  Copper acetoarsenite (12002-03-8): C4H6As6Cu4O16 
The Molecular Weight of Copper acetoarsenite (12002-03-8): 1013.7944 
Molecular Structure of  Copper acetoarsenite (12002-03-8):

Appearance: bluish-green powder

Toxicity Data With Reference

1.    

orl-rat LD50:22 mg/kg

    PCOC**    Pesticide Chemicals Official Compendium ,Association of the American Pesticide Control Officials, Inc.(Topeka, KS.: ),1966,254.
2.    

unk-mam LD50:18 mg/kg

    30ZDA9    Chemistry of Pesticides .Melnikov, N.N.,New York, NY.: Springer-Verlag,1971,388.

Consensus Reports

EPA Extremely Hazardous Substances List. Arsenic and its compounds, as well as copper and its compounds, are on the Community Right-To-Know List.

Safety Profile

Poison by ingestion and possibly other routes. An insecticide. When heated to decomposition it emits very toxic fumes of As. See also ARSENIC COMPOUNDS and COPPER COMPOUNDS.
Safety Information about Copper acetoarsenite (12002-03-8):
RIDADR: 1585
HazardClass: 6.1(a)
PackingGroup: II

Standards and Recommendations

OSHA PEL: TWA 0.5 mg(As)/m3
DOT Classification:  6.1; Label: Poison

Specification

  The chemical synonyms of Copper acetoarsenite (12002-03-8) are (Acetato)trimetaarsenitodicopper ; (Acetato-O)(trimetaarsenito)dicopper ; Acetoarsenite de cuivre ; Acetoarsenite de cuivre [French] ; Basle Green ; C.I. 77410 ; CCRIS 4771 ; CI 77410 ; CI Pigment Green 21 ; Caswell No. 229A ; Copper acetate arsenite ; Copper aceto-arsenite ; Copper(II) acetate meta-arsenate ; Copper, bis(acetato)hexametaarsenitotetra- ; Cupric acetoarsenite ; ENT 884 ; EPA Pesticide Chemical Code 022601 ; French Green ; Genuine Paris Green ; HSDB 1824 ; Imperial Green ; King's Green ; Meadow Green ; Mineral Green ; Mitis Green ; Moss Green ; Mountain Green ; Neuwied Green ; New Green ; Ortho P-G bait ; Paris Green ; Parrot Green ; Patent Green ; Powder Green ; Schweinfurt Green ; Schweinfurtergrun ; Schweinfurth Green ; Sowbug & cutworm bait ; Sowbug cutworm control ; Swedish Green ; Vienna Green ; Wuerzberg Green ; Zwickau Green . Some absorption may occur through the skin and by inhalation, but most poisonings result from ingestion. It may cause eye and respiratory tract irritation. Industrial exposure may cause dermatitis.Decomposes readily in the presence of water and carbon dioxide to yield phytotoxic arsenical compounds. Can react vigorously with oxidizing materials. Unstable in acids and bases. Hazardous polymerization may not occur.