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12054-48-7

Basic Information
CAS No.: 12054-48-7
Name: Nickel(III) hydroxide
Molecular Structure:
Molecular Structure of 12054-48-7 (Nickel(III) hydroxide)
Formula: H2NiO2
Molecular Weight: 92.71 .
Synonyms: Nickeldihydroxide;Nickel hydroxide;Nickel(2+) hydroxide;Nickelous hydroxide;Nickel(II) hydroxide;
EINECS: 235-008-5
Density: 4.10 g/cm3
Melting Point: 230 °C (dec.)
Boiling Point: 100 °C at 760 mmHg
Appearance: Apple green powder
Hazard Symbols: HarmfulXn, DangerousN
Risk Codes: 20/22-40-43-50/53
Safety: 22-36-60-61
Transport Information: UN 3077 9/PG 3
PSA: 40.46000
LogP: -0.35360
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    Nickel Hydroxide

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  • Nickel(II) hydroxide

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    Nickel(II) hydroxide

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    Name: Nickel Hydroxide CAS: 12054-48-7 Molecular Formula: Ni(OH)2 Molecular Weight: 92.7047 Application:Fine chemical

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  • Acmec Nickel(II) hydroxide 500g

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    Acmec Nickel(II) hydroxide 500g

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Consensus Reports

NTP 10th Report on Carcinogens. IARC Cancer Review: Group 1 IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 ,1987,p. 264.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Sufficient Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 11 ,1976,p. 75.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . Nickel and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.

Standards and Recommendations

OSHA PEL: TWA 0.1 mg (Ni)/m3
ACGIH TLV: TWA 0.2 mg(Ni)/m3; Human Carcinogen
NIOSH REL: (Inorganic Nickel) TWA 0.015 mg(Ni)/m3

Specification

The Nickel(II) hydroxide is an organic compound with the formula H2NiO2. The IUPAC name of this chemical is nickel dihydrate. With the CAS registry number 12054-48-7, it is also named as Nickel(2+) dihydroxide. The product's categories are Inorganics; Metal and Ceramic Science; Nickel Salts; Salts. Besides, it is an apple green powder, which should be stored in cool and ventilated place. It can be used for making nickel salt, alkaline batteries and nickel-plated, and can be used as alkaline batteries, electroplating, catalysts.Its physical properties are:(1)#H bond acceptors:  2; (2)#H bond donors:  2; (3)#Freely Rotating Bonds:  2; (4)mp: 230°C (dec.); (5)density: 4.1g/mL(lit.); (6)Merck: 13,6534.

Preparation of Nickel(II) hydroxide:
This chemical can be prepared by Nickel sulphate and sodium hydroxide. Chemical reaction equation is as follows:

Safety information of Nickel(II) hydroxide:
When you are using Nickel(II) hydroxide, please be cautious about it as the following:It is harmful by inhalation and if swallowed and may cause sensitisation by skin contact. It has limited evidence of a carcinogenic effect. Besides, this chemical Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. When you are using it, wear suitable protective clothing and do not breathe dust. This material and its container must be disposed of as hazardous waste.

You can still convert the following datas into molecular structure:
(1)SMILES:O[Ni]O;
(2)Std. InChI:InChI=1S/Ni.2H2O/h;2*1H2/q+2;;/p-2;
(3)Std. InChIKey:BFDHFSHZJLFAMC-UHFFFAOYSA-L.

The toxicity data of Nickel(II) hydroxide is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 subcutaneous 50mg/kg (50mg/kg)   Zhurnal Vsesoyuznogo Khimicheskogo Obshchestva im. D.I. Mendeleeva. Journal of the D.I. Mendeleeva All-Union Chemical Society. Vol. 19, Pg. 186, 1974.
rat LC50 inhalation 1200mg/m3/4H (1200mg/m3) BEHAVIORAL: EXCITEMENT

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

SKIN AND APPENDAGES (SKIN): HAIR: OTHER
Research and Consulting Company, Technical Reports. Vol. NOTOX1074, Pg. 1988,
rat LD50 oral 1515mg/kg (1515mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: ATAXIA

GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"
Acute Toxicity Data. Journal of the American College of Toxicology, Part B. Vol. 1, Pg. 684, 1992.
rat LD50 skin > 2gm/kg (2000mg/kg)   Research and Consulting Company, Technical Reports. Vol. NOTOX1074/1338, Pg. 1988,