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1314-34-7

Basic Information
CAS No.: 1314-34-7
Name: VANADIUM (III) OXIDE
Molecular Structure:
Molecular Structure of 1314-34-7 (VANADIUM (III) OXIDE)
Formula: O3V2
Molecular Weight: 149.88
Synonyms: Divanadiumtrioxide;Vanadic oxide;Vanadium sesquioxide;Vanadium trioxide;Vanadium(3+)oxide;
EINECS: 215-230-9
Density: 4.87 g/mL at 25 °C(lit.)
Melting Point: 690 °C(lit.)
Boiling Point: 3000℃[at 101 325 Pa]
Solubility: Slightly soluble in water.
Appearance: black powder
Hazard Symbols: HarmfulXn
Risk Codes: 20-36/37/38
Safety: 26
Transport Information: UN 2862 6.1/PG 3
PSA: 43.37000
LogP: -0.30600
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Chemistry


IUPAC Name: Vanadium oxide 
Molecular Formula: O3V2
Molecular Weight: 149.8812 g/mol
Canonical SMILES: O=[V]O[V]=O
InChI: InChI=1S/3O.2V
EINECS: 215-239-8
Classification Code: Mutation data; Skin / Eye Irritant
Melting Point: 690 °C(lit.)
Stability: Stable. Air sensitive.
Density of Vanadium trioxide (CAS NO.1314-34-7): 4.87 g / cm3

Uses

 Vanadium trioxide (CAS NO.1314-34-7) is used as catalyst and to make other chemicals.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 oral 130mg/kg (130mg/kg)   "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 119, 1982.
mouse LD50 subcutaneous 130mg/kg (130mg/kg)   Zhurnal Vsesoyuznogo Khimicheskogo Obshchestva im. D.I. Mendeleeva. Journal of the D.I. Mendeleeva All-Union Chemical Society. Vol. 19, Pg. 186, 1974.
rabbit LD50 skin 200mg/kg (200mg/kg) KIDNEY, URETER, AND BLADDER: OTHER CHANGES National Technical Information Service. Vol. OTS0534591,
rat LD50 oral 566mg/kg (566mg/kg) LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES

LIVER: OTHER CHANGES

KIDNEY, URETER, AND BLADDER: OTHER CHANGES
National Technical Information Service. Vol. OTS0534591,
rat LDLo intratracheal 125mg/kg (125mg/kg)   National Technical Information Service. Vol. AEC-TR-6710,

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by ingestion, subcutaneous, and intratracheal routes. Ignites when heated in air. When heated to decomposition it emits toxic fumes of VOx
Hazard Codes: HarmfulXn
Risk Statements: 20-36/37/38 
R20:Harmful by inhalation. 
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
RIDADR: UN 2862 6.1/PG 3
WGK Germany: 3
RTECS of Vanadium trioxide (CAS NO.1314-34-7): YW3050000

Standards and Recommendations

ACGIH TLV: TWA 0.05 mg(V2O5)/m3
NIOSH REL: (Vanadium Compound) CL 0.05 mg(V)/m3/15M

Analytical Methods

For occupational chemical analysis use NIOSH: Vanadium Oxides, 7504.

Specification

  Vanadium trioxide (CAS NO.1314-34-7), its Synonyms are Divanadium trioxide ; Vanadium oxide ; Vanadium oxide (V2O3) ; Vanadium oxide, sesqui ; Vanadium sesquioxide ; Vanadium(3+) oxide . It is black powder.