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1314-56-3

Basic Information
CAS No.: 1314-56-3
Name: Phosphorus pentoxide
Molecular Structure:
Molecular Structure of 1314-56-3 (Phosphorus pentoxide)
Formula: O10P4
Molecular Weight: 283.89
Synonyms: Nutrition,plantphosphorus Phosphorus;Phosphorpentoxid;Phospholus Pentoxide;Phosphoric Pentoxide;Phosphoric anhydride;
EINECS: 215-236-1
Density: 2.46 g/cm3
Melting Point: 340 °C(lit.)
Boiling Point: 122 °C (1 mmHg)
Flash Point: 340-360°C
Solubility: Soluble in sulfuric acid. Insoluble in acetone and ammonia. Decomposes in water.
Appearance: white to yellow crystalline powder
Hazard Symbols: CorrosiveC
Risk Codes: 35
Safety: 22-26-45
Transport Information: UN 1807 8/PG 2
PSA: 145.79000
LogP: 1.17880
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    Rock Phosphate P2O5 Fertilizer powderAppearance:powder Package:aluminium foil bag drum Application:in research Transportation:By express (Door to door) such as FEDEX, DHL, EMS for small amount. By air(airport to airport) or by sea LCL/FCL for large a

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  • Phosphorus pentoxide

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    Phosphorus pentoxide

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    bulk?production Application:Pharmaceutical intermediates

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  • Phosphorus pentoxide

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    1314-56-3

    Phosphorus pentoxide

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  • Phosphorus Pentoxide

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    1314-56-3

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    Phosphorus Pentoxide

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    1、Technology:The ONLY supplier in China for P2O5 with 1PPM As content; 2、Raw material: Stable raw material supply,self-owned rock phosphate mine and capacity of Low arsenic yellow phosphorus around 1000 tons/y; 3、Production: Ex

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Consensus Reports

Reported in EPA TSCA Inventory.

Standards and Recommendations

DFG MAK: 1 mg/m3
DOT Classification:  8; Label: Corrosive

Specification

The Phosphorus pentoxide, also known as Phosphoric acid anhydride, is the organic compound with the formula O10P4. It belongs to the product categories of Inorganic Chemicals; Inorganics; Element oxide. Its EINECS registry number is 215-236-1. With the CAS registry number 1314-56-3, its systematic name is Tricyclo[3.3.1.13,7]tetraphosphoxane 1,3,5,7-tetraoxide. This white crystalline solid is the anhydride of phosphoric acid. It is a powerful desiccant. Phosphorus pentoxide is not flammable. It reacts vigorously with water and water-containing substances like wood or cotton, liberates much heat and may even cause fire.

Physical properties of Phosphorus pentoxide: (1)ACD/LogP: 6.399; (2)# of Rule of 5 Violations: 2; (3)ACD/LogD (pH 5.5): 6.40; (4)ACD/LogD (pH 7.4): 6.40; (5)ACD/BCF (pH 5.5): 42989.39; (6)ACD/BCF (pH 7.4): 42989.39; (7)#H bond acceptors: 10; (8)Index of Refraction: 1.491; (9)Molar Refractivity: 33.323 cm3; (10)Molar Volume: 115.059 cm3; (11)Surface Tension: 84.367 dyne/cm; (12)Density: 2.467 g/cm3.

Preparation of Phosphorus pentoxide: Phosphorus pentoxide is prepared by burning elemental phosphorus with sufficient supply of air:
P4 + 5 O2 → P4O10

Uses of Phosphorus pentoxide: 
Phosphorus pentoxide is a potent dehydrating agent as indicated by the exothermic nature of its hydrolysis:
P4O10 + 6 H2O → 4 H3PO4 (–177 kJ)
However, its utility for drying is limited somewhat by its tendency to form a protective viscous coating that inhibits further dehydration by unspent material. A granular form of P4O10 is used in desiccators.

Consistent with its strong desiccating power, P4O10 is used in organic synthesis for dehydration. The most important application is for the conversion of amides into nitriles:
P4O10 + RC(O)NH2 → P4O9(OH)2 + RCN

The indicated coproduct P4O9(OH)2 is an idealized formula for undefined products resulting from the hydration of P4O10.
Alternatively, when combined with a carboxylic acid, the result is the corresponding anhydride:
P4O10 + RCO2H → P4O9(OH)2 + [RC(O)]2O

When you are using this chemical, please be cautious about it as the following:
This chemical may destroy living tissue on contact and may cause burns. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. Whenever you will contact it, please wear suitable protective clothing, gloves and eye/face protection.

You can still convert the following datas into molecular structure:
(1)InChI: InChI=1S/O10P4/c1-11-5-12(2)8-13(3,6-11)10-14(4,7-11)9-12
(2)InChIKey: DLYUQMMRRRQYAE-UHFFFAOYSA-N
(3)Canonical SMILES : O=P12OP3(=O)OP(=O)(O1)OP(=O)(O2)O3

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
guinea pig LC50 inhalation 61mg/m3/1H (61mg/m3) LUNGS, THORAX, OR RESPIRATION: CHRONIC PULMONARY EDEMA

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES

BLOOD: HEMORRHAGE
Toxicologist. Vol. 1, Pg. 140, 1981.
mouse LC50 inhalation 271mg/m3/1H (271mg/m3) LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES

LUNGS, THORAX, OR RESPIRATION: CHRONIC PULMONARY EDEMA

BLOOD: HEMORRHAGE
Toxicologist. Vol. 1, Pg. 140, 1981.
rabbit LC50 inhalation 1689mg/m3/1H (1689mg/m3) LUNGS, THORAX, OR RESPIRATION: CHRONIC PULMONARY EDEMA

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES

BLOOD: HEMORRHAGE
Toxicologist. Vol. 1, Pg. 140, 1981.
rat LC50 inhalation 1217mg/m3/1H (1217mg/m3) LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES

LUNGS, THORAX, OR RESPIRATION: CHRONIC PULMONARY EDEMA

BLOOD: HEMORRHAGE
Toxicologist. Vol. 1, Pg. 140, 1981.

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