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| CAS No.: | 13424-46-9 |
|---|---|
| Name: | Lead azide |
| Article Data: | 43 |
| Molecular Structure: | |
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|
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| Formula: | N6Pb |
| Molecular Weight: | 291.24 |
| Synonyms: | Lead azide;Lead azide (PbN6); Lead diazide; Lead(2+) azide; RD 1333 |
| Density: | g/cm3 |
| Boiling Point: | °Cat760mmHg |
| Flash Point: | °C |
| Solubility: | 0.023% H2O (18°C), 0.09% (70°C) [MER06]; insoluble NH4OH; very soluble acetic acid [KIR78] |
| Hazard Symbols: | Severe explosion risk, detonates at 350C (660F). Highly toxic. TLV: 0.15 mg(Pb)/m3. |
| Risk Codes: | 61-3-20/22-33-50/53-62 |
| Safety: | A deadly poison. An explosive sensitive to shock or heating to 250°C. Will explode spontaneously during crystallization. Mixtures with calcium stearate may explode spontaneously. May explode spontaneously after prolonged contact with copper, zinc, or their alloys (e.g., brass). Incompatible with CS2. Used in commercial blasting caps and military ammunition. When heated it emits highly toxic fumes of Pb and NOx. See also LEAD COMPOUNDS, AZIDES, and EXPLOSIVES, HIGH. |
| PSA: | 24.72000 |
| LogP: | -0.39740 |
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Chemistry
IUPAC Name: Diazidolead
CAS: 13424-46-9
EINECS: 236-542-1
Product Categories: Inorganics
Following is the Molecular Structure of Lead(II) azide (13424-46-9):
SMILES: [N-]=[N+]=[N-].[N-]=[N+]=[N-].[Pb+2]
InChI: InChI=1/2N3.Pb/c2*1-3-2;/q2*-1;+2
InChIKey: ISEQAARZRCDNJH-UHFFFAOYAO
Std.InChI: InChI=1S/2N3.Pb/c2*1-3-2;/q2*-1;+2
Std.InChIKey: ISEQAARZRCDNJH-UHFFFAOYSA-N
Molecular Formula: N6Pb
Molecular Weight: 291.24
Uses
Used in commercial blasting caps and military ammunition.
Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| rat | LD | intraperitoneal | > 150mg/kg (150mg/kg) | Public Health Reports. Vol. 58, Pg. 607, 1943. |
Consensus Reports
Lead and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.
Safety Profile
Hazard Codes: .gif){kind=small}
E Explosive , 
T Toxic ,
N Dangerous for the environment.
Risk Statements: 61-3-20/22-33-50/53-62
R61: May cause harm to the unborn child.
R3: Extreme risk of explosion by shock,friction,fire or other sources of ignition.
R20/22: Harmful by inhalation and if swallowed.
R33: Danger of cumulative effects.
R50/53: Very Toxic to aquatic organisms,may cause long-term adverse effects in the aquatic environment.
R62: Possible risk of impaired fertility.
Safety Statements: 53-45-60-61
S53: Avoid exposure-obtain special instruction before use.
S45: In case of accident or if you feel unwell,seek medical advice immediately (show label where possible).
S60: This material and/or its container must be disposed of as hazardous waste.
S61: Avoid release to the environment. Refer to special instructions safety data sheet.
RIDADR: 0129
HazardClass: 1.1A
PackingGroup: II
A deadly poison. An explosive sensitive to shock or heating to 250℃. Will explode spontaneously during crystallization. Mixtures with Calcium stearate may explode spontaneously. May explode spontaneously after prolonged contact with Copper , Zinc ,or their alloys (e.g. brass). Incompatible with CS2 .
Standards and Recommendations
OSHA PEL: TWA 0.05 mg(Pb)/m3
ACGIH TLV: TWA 0.15 mg(Pb)/m3
NIOSH REL: (Inorganic Lead) TWA 0.10 mg(Pb)/m3
DOT Classification: Forbidden (dry)
Specification
Lead(II) azide (13424-46-9),which also can be called for Lead azide ; Lead diazide ; Plumbous azide ; Lead azide (Pb(N3)2) ; Lead(II) azide. ; Lead diazide lead azide ; Diazidolead(II) ; Lead(II)diazide . Lead(II) azide (13424-46-9) is a needles or white powder.It's unstable.When heated it emits highly toxic fumes of Pb and NOx .