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135616-40-9

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CAS No.: 135616-40-9
Name: (R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine
Article Data: 9
Molecular Structure:
Molecular Structure of 135616-40-9 ((R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine)
Formula: C36H54N2O2
Molecular Weight: 546.837
Synonyms: (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE;(R,R)-(-)-N,N'-BIS(3.5-DI-T-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE;(R,R)-JACOBSEN LIGAND;(R,R)-JACOBSEN'S LIGAND;(1R,2R)-(-)-1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE);(R,R)-(-)-N,N'-BIS(3,5-DI-T-BU-SALICYL.)-1 ,2-CYCLOHEXANDIAM.;(R,R)-(-)-N,N'-Bis(3,5-di-t-bu-salicyl.)-1,2-cyclohexanedia;(1R,2R)-(-)-1,2-CYCLOHEXANEDIAMINO-N,N'-BIS-(3,5-DI-TERT-BUTYLSALICYLIDENE)
Density: 1.01 g/cm3
Melting Point: 205-207ºC
Boiling Point: 615.2 °C at 760 mmHg
Flash Point: 421.6 °C
Appearance: white crystal powder
Hazard Symbols:
Risk Codes: R36/37/38   
Safety: S26
PSA: 65.18000
LogP: 9.13700
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Chemistry

Molecular Structure:

Molecular Formula: C36H54N2O2
Molecular Weight: 546.8262
IUPAC Name: 2,4-ditert-butyl-6-[[[(1R,2R)-2-[(3,5-ditert-butyl-6-oxocyclohexa-2,4-dien-1-ylidene)methylamino]cyclohexyl]amino]methylidene]cyclohexa-2,4-dien-1-one
Synonyms of (R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine (CAS NO.135616-40-9): (R,R)-Jacobsen ligand ; (R,R)-Jacobsen's ligand ; (1R,2R)-(-)-1,2-Cyclohexanediamino-n n'-bis(3,5-di-t-butylsalicylidene) ; (1R,2R)-(-)-1,2-Cyclohexanediamino-n,n'-bis-(3,5-di-tert-butylsalicylidene)
CAS NO: 135616-40-9
Melting point: 205-207 °C 
Index of Refraction: 1.535
Molar Refractivity: 168.53 cm3
Molar Volume: 540.7 cm3
Surface Tension: 33.4 dyne/cm
Density: 1.01 g/cm3
Flash Point: 421.6 °C
Enthalpy of Vaporization: 94.61 kJ/mol
Boiling Point: 615.2 °C at 760 mmHg
Vapour Pressure: 1E-15 mmHg at 25°C

Safety Profile

Hazard Codes of (R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine (CAS NO.135616-40-9): IrritantXi
Risk Statements: 36/37/38 
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36: Wear suitable protective clothing.
WGK Germany: 3