CAS No.14167-18-1,Salcomine Suppliers

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Basic Information

Molecular Structure:
CAS No.:	14167-18-1
Name:	Salcomine
Article Data:	46

Formula:	C₁₆H₁₄CoN₂O₂
Molecular Weight:	325.293
Synonyms:	Cobalt salen;N,N'-Ethylenebis(salicylideniminato)cobalt(II);NSC 32965;Salcomin;Salcomine;[2,2'-[Ethane-1,2-diylbis(nitrilomethylidene)]diphenolato]cobalt(II);[Bis(salicylidene)ethylenediaminato]cobalt;[Bis(salicylidene)ethylenediamine]cobalt;[N,N'-Bis(salicylidene)ethylenediaminato]cobalt;[N,N'-Disalicylideneethylenediamine]cobalt;[N,N'-Ethylenebis(salicylaldehydeiminato)]cobalt(II);[N,N'-Ethylenebis(salicylideniminato)]cobalt;Cobalt,[[2,2'-[1,2-ethanediylbis(nitrilomethylidyne)]bis[phenolato]](2-)-N,N',O,O']-,(SP-4-2)-;Cobalt, [[a,a'-(ethylenedinitrilo)di-o-cresolato](2-)]-(7CI,8CI);o-Cresol, a,a'-(ethylenedinitrilo)di-, Coderiv. (6CI);(N,N'-Bis(salicylidene)ethylenediamine)cobalt(II);Bis(salicylidene)ethylenediaminatocobalt(II);Co(salen);Cobaltbis(salicylidene)ethylenediamine;
EINECS:	238-012-5
Melting Point:	>300 °C
Boiling Point:	498.2ºC at 760 mmHg
Solubility:	Insoluble in water. Soluble in benzene, chloroform, and pyridine.
Appearance:	black crystalline powder
Hazard Symbols:	Xi
Risk Codes:	36/37/38
Safety:	26-36
PSA:	43.18000
LogP:	1.78200

Total:38 Page 1 of 1 1

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Consensus Reports

Reported in EPA TSCA Inventory. Cobalt and its compounds are on the Community Right-To-Know List. EPA Extremely Hazardous Substances List.

Specification

The Salcomine, with the CAS registry number 14167-18-1 and EINECS registry number 238-012-5, has the IUPAC name of cobalt(2+); 2-[2-[(2-oxidophenyl)methylideneamino]ethyliminomethyl]phenolate. And the molecular formula of this chemical is C₁₆H₁₄CoN₂O₂. It is a kind of black crystalline powder, and belongs to the following product categories: Catalysts for Organic Synthesis; Classes of Metal Compounds; Co (Cobalt) Compounds; Homogeneous Catalysts; Metal Complexes; Synthetic Organic Chemistry; Transition Metal Compounds.

The physical properties of Salcomine are as following: (1)#H bond acceptors: 4; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 0; (4)Polar Surface Area: 43.18 Å².

Preparation and uses of Salcomine: It can be easily synthesized from cobalt(II) acetate and salenH₂. And it reversibly bound O₂ led to intensive research on salen and related ligands for the storage or transport of oxygen. It is used as catalyst in the oxidation of 2,6-disubstituted phenols by dioxygen.

You should be cautious while dealing with this chemical. It irritates eyes, respiratory system and skin. Therefore, you had better take the following instructions: Wear suitable protective clothing, and in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)SMILES: C1CN=Cc3ccccc3O[Co]Oc2ccccc2C=N1
(2)InChI: InChI=1/C16H16N2O2.Co/c19-15-7-3-1-5-13(15)11-17-9-10-18-12-14-6-2-4-8-16(14)20;/h1-8,11-12,19-20H,9-10H2;/q;+2/p-2
(3)InChIKey: NPAQSKHBTMUERN-NUQVWONBAY

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LCLo	inhalation	390mg/m³/5.5H (390mg/m³)	LUNGS, THORAX, OR RESPIRATION: STRUCTURAL OR FUNCTIONAL CHANGE IN TRACHEA OR BRONCHI LUNGS, THORAX, OR RESPIRATION: CHRONIC PULMONARY EDEMA LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES	Aerospace Medical Research Laboratory Report. Vol. TR-74-78, Pg. 1974,