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14221-47-7

Basic Information
CAS No.: 14221-47-7
Name: Ferric ammonium oxalate
Molecular Structure:
Molecular Structure of 14221-47-7 (Ferric ammonium oxalate)
Formula: C6H12FeN3O12
Molecular Weight: 374.06
Synonyms: Ammoniumtris(oxalato)ferrate(III) (6CI,7CI);Ferrate(3-), tris(oxalato)-, triammonium(8CI);Ferrate(3-), tris[ethanedioato(2-)-O,O']-, triammonium, (OC-6-11)-;Ferrate(3-), tris[ethanedioato(2-)-kO1,kO2]-, triammonium, (OC-6-11)-(9CI);Ammonium ferric oxalate;Ammonium ferrioxalate;Triammonium iron trioxalate;Triammonium trioxalatoferrate;Triammoniumtrioxalatoferrate(3-);Triammonium tris(oxalato)ferrate(3-);Tris(ammonium)trioxalatoferrate(3-);
EINECS: 238-090-0
Density: d17.5 1.78
Boiling Point: 365.1 °C at 760 mmHg
Flash Point: 188.8 °C
Solubility: soluble in water
Appearance: Green crystals
Transport Information: UN 9119
PSA: 200.52000
LogP: -1.79530
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Chemistry

Molecular Formula: C6H12FeN3O12
Molar mass: 374.02 g/mol
EINECS: 238-090-0
Flash Point: 188.8 °C
Boiling Point: 365.1 °C at 760 mmHg
Vapour Pressure: 2.51E-06 mmHg at 25°C
Water solubility: Soluble
Product categories of Ammonium ferrioxalate (14221-47-7): Industrial/Fine Chemicals;Organic-metal salt
Structure of Ammonium ferrioxalate (14221-47-7):

H-Bond Donor: 3
H-Bond Acceptor: 12
IUPAC Name: Triazanium; iron(3+); oxalate
Canonical SMILES: C(=O)(C(=O)[O-])[O-].C(=O)(C(=O)[O-])[O-].C(=O)(C(=O)[O-])[O-].[NH4+].
[NH4+].[NH4+].[Fe+3]
InChI: InChI=1S/3C2H2O4.Fe.3H3N/c3*3-1(4)2(5)6;;;;/h3*(H,3,4)(H,5,
6);;3*1H3/q;;;+3;;;/p-3 
InChIKey: UEUDBBQFZIMOQJ-UHFFFAOYSA-K

Uses

 Ammonium ferrioxalate (14221-47-7) can be used for coloring of aluminum and aluminum alloy, photography,  the electroplating industry, etc.

Toxicity Data With Reference

1.    

skn-rbt 500 mg MOD

    FCTOD7    Food and Chemical Toxicology. 20 (1982),563.
2.    

eye-rbt 100 mg MOD

    FCTOD7    Food and Chemical Toxicology. 20 (1982),573.
3.    

eye-rbt 100 mg/4 S rns MLD

    FCTOD7    Food and Chemical Toxicology. 20 (1982),573.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

An eye and skin irritant. When heated to decomposition it emits toxic fumes of NH3. See also OXALATES.

Specification

 Ammonium ferrioxalate (14221-47-7) also can be called Triammonium trioxalatoferrate ; Triammonium trioxalatoferrate(3-) ; Triammonium tris(oxalato)ferrate(3-) ; Ammonium ferric oxalate .