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| CAS No.: | 14694-95-2 |
|---|---|
| Name: | Chlorotris(triphenylphosphine)rhodium(I) |
| Article Data: | 51 |
| Molecular Structure: | |
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|
|
| Formula: | C54H45ClP3Rh |
| Molecular Weight: | 925.231 |
| Synonyms: | Rhodium,chlorotris(triphenylphosphine)- (7CI,8CI);Chlorotris(triphenylphosphine)rhodium(I);NSC 124140;Rhodium tris(triphenylphosphine) chloride;Tris(triphenylphosphine)rhodiumchloride;Tris(triphenylphosphine)rhodium(I)chloride;Wilkinson's catalyst; |
| EINECS: | 238-744-5 |
| Density: | 1.363; d 1.379 |
| Melting Point: | 245-250 °C (dec.) |
| Boiling Point: | >170 °C |
| Flash Point: | 181.7oC |
| Solubility: | insoluble in water |
| Appearance: | magenta crystals |
| Hazard Symbols: |
 Xi, C
|
| Risk Codes: | 34-36/38 |
| Safety: | 22-24/25-37/39-28A-26-15 |
| PSA: | 40.77000 |
| LogP: | 11.02390 |
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Specification
The Rhodium,chlorotris(triphenylphosphine)-, (SP-4-2)-, with the CAS registry number 14694-95-2 and EINECS registry number 238-744-5, has the systematic name of chlororhodium; triphenylphosphane. It is a kind of magenta crystals, and belongs to the following product categories: Metal Compounds; Catalysts for Organic Synthesis; Classes of Metal Compounds; Homogeneous Catalysts; Metal Complexes; Rh (Rhodium) Compounds; Synthetic Organic Chemistry; Transition Metal Compounds. And the molecular formula of this chemical is C54H45ClP3Rh. What's more, it is soluble in benzene and toluene while insoluble in ether or alcohol. And it is often used as hydrogenation catalyst and Wilkinson catalyst. And it should be stored at 2-8°C.
The physical properties of Rhodium,chlorotris(triphenylphosphine)-, (SP-4-2)- are as followings: (1)#H bond acceptors: 0; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 9; (4)Polar Surface Area: 40.77 Å2.
You should be cautious while dealing with this chemical. It irritates to eyes and skin, and it may also cause burns. Therefore, you had better take the following instructions: Wear suitable gloves and eye/face protection, and in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice; Do not breathe dust; Avoid contact with skin and eyes; After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer); Keep away from heat.
You can still convert the following datas into molecular structure:
(1)SMILES: Cl[Rh].c1ccccc1P(c2ccccc2)c3ccccc3.c1ccccc1P(c2ccccc2)c3ccccc3.c1ccccc1P(c2ccccc2)c3ccccc3
(2)InChI: InChI=1/3C18H15P.ClH.Rh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/q;;;;+1/p-1/r3C18H15P.ClRh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2/h3*1-15H;
(3)InChIKey: IXAYKDDZKIZSPV-CMQSVACPAK