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| CAS No.: | 1934-21-0 |
|---|---|
| Name: | Acid Yellow 23 |
| Molecular Structure: | |
|
|
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| Formula: | C16H9N4Na3O9S2 |
| Molecular Weight: | 534.37 |
| Synonyms: | 1H-Pyrazole-3-carboxylicacid, 4,5-dihydro-5-oxo-1-(4-sulfophenyl)-4-[2-(4-sulfophenyl)diazenyl]-,sodium salt (1:3);A.F. Yellow No.4;AY 23;AtulTartrazine;B 3014;Bosovit Yellow 133E;C.I. 19140;C.I. Food Yellow 4;C.I. Solvent Yellow 57;Calcocid Yellow XX;Canacert Tartrazine;Certicol Tartrazol YellowS;Cilefa Yellow T;Cogilor Yellow 113.11;Concorde Acid Tartrazine;Curon Fast Yellow 5G;D and C Yellow No. 5;C Yellow 5;Dinacid Tartarzine Yellow PFD;Duasyn Acid Yellow XX;Duasyn Acid Yellow XX-SF-LP 413;Dyacid Yellow N;Dynacid Yellow K;E 102;EdicolSupra Tartrazine N;Egg Yellow A;ErioTartrazine;Eurocert Tartrazine;C Yellow No. 5-307008;FD and C Yellow No. 5;C Yellow5;C Yellow No.5-37009;Fenazo Yellow T;FoodYellow 4;Food dye yellow number 4;HD Tartrazine; |
| EINECS: | 217-699-5 |
| Density: | 1.93 g/cm3 (20ºC) |
| Melting Point: | 300 °C |
| Boiling Point: | 909.54℃[at 101 325 Pa] |
| Solubility: | water: 260 g/L (30 °C) |
| Appearance: | Deep yellow powder |
| Hazard Symbols: |
 Xn
|
| Risk Codes: | 42/43 |
| Safety: | 22-36/37-45-24/25 |
| PSA: | 220.19000 |
| LogP: | 2.78190 |
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Consensus Reports
Specification
The IUPAC name of Acid Yellow 23 is trisodium 5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4H-pyrazole-3-carboxylate. With the CAS registry number 1934-21-0, it is also named as 1H-Pyrazole-3-carboxylic acid, 4,5-dihydro-5-oxo-1-(4-sulfophenyl)-4-((4-sulfophenyl)azo)-, trisodium salt; Tartrazine. The product's categories are dyes and pigments; organics; analytical chemistry; food colors by food sanitation law in Japan. It is deep yellow powder which is soluble in water, glycerin and propylene glycol, slightly soluble in ethanol. In addition, this chemical is stable, hygroscopic and incompatible with strong oxidizing agents. it must be stored in a cool, dry place and keep container closed when not in use. Furthermore, Acid Yellow 23 is used as colorant for food, beverage, medicine, feed and cosmetic.
The other characteristics of this product can be summarized as: (1)#H bond acceptors: 13; (2)#H bond donors: 4; (3)#Freely Rotating Bonds: 6; (4)Rotatable Bond Count: 3; (5)Tautomer Count: 4; (6)Exact Mass: 533.950403; (7)MonoIsotopic Mass: 533.950403; (8)Topological Polar Surface Area: 229; (9)Heavy Atom Count: 34; (10)Complexity: 949; (11)Undefined Atom StereoCenter Count: 1; (12)Covalently-Bonded Unit Count: 4.
Preparation of Acid Yellow 23: It can be obtained by the condensation of two-hydroxy-tartaric acid and phenylhydrazine-p-sulfonic acid. Or coupling 1-(4'-sulfophenyl)-3-carboxy-5-pyrazolidone and sulfanilic acid which is diazotization, then salting with sodium chloride. Finally, we can get the product by purification.
When you are using this chemical, please be cautious about it as the following:
It may cause sensitization by inhalation and skin contact, so people should not breathe dust and avoid contact with skin and eyes. If you want to contact this product, you must wear suitable protective clothing and gloves. In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
People can use the following data to convert to the molecule structure.
1. SMILES: c1cc(ccc1N=Nc2c([nH]n(c2=O)c3ccc(cc3)S(=O)(=O)[O-])C(=O)[O-])S(=O)(=O)[O-].[Na+].[Na+].[Na+];
2. InChI: InChI=1/C16H12N4O9S2.3Na/c21-15-13(18-17-9-1-5-11(6-2-9)30(24,25)26)14(16(22)23)19-20(15)10-3-7-12(8-4-10)31(27,28)29;;;/h1-8,19H,(H,22,23)(H,24,25,26)(H,27,28,29);;;/q;3*+1/p-3/b18-17+;;;.
The following are the toxicity data which has been tested.
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| human | TDLo | oral | 14ug/kg (0.014mg/kg) | PERIPHERAL NERVE AND SENSATION: PARESTHESIS MUSCULOSKELETAL: CHANGES IN TEETH AND SUPPORTING STRUCTURES | Annals of Allergy. Vol. 17, Pg. 719, 1959. |
| mouse | LD50 | oral | 12750mg/kg (12750mg/kg) | FAO Nutrition Meetings Report Series. Vol. 38B, Pg. 88, 1966. | |
| rat | LD50 | intraperitoneal | > 2gm/kg (2000mg/kg) | FAO Nutrition Meetings Report Series. Vol. 38B, Pg. 88, 1966. | |
| rat | LD50 | intravenous | > 2gm/kg (2000mg/kg) | Annales Pharmaceutiques Francaises. Vol. 15, Pg. 402, 1957. |