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Basic Information
CAS No.: 2116-65-6
Name: 4-Benzylpyridine
Article Data: 66
Molecular Structure:
Molecular Structure of 2116-65-6 (4-Benzylpyridine)
Formula: C12H11N
Molecular Weight: 169.226
Synonyms: Pyridine,4-benzyl- (6CI,7CI,8CI);4-(Phenylmethyl)pyridine;Ba 33216;CDD 3513;NSC 8075;g-Benzylpyridine;
EINECS: 218-319-0
Density: 1.044 g/cm3
Melting Point: 9-11 °C
Boiling Point: 285.1 °C at 760 mmHg
Flash Point: 115 °C
Solubility: Soluble in ethanol, ethyl ether. Insoluble in water.
Appearance: clear slightly yellow liquid
Hazard Symbols: HarmfulXn
Risk Codes: 22-36/37/38
Safety: 26-36
PSA: 12.89000
LogP: 2.67240
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Chemistry

IUPAC Name: 4-Benzylpyridine
Synonyms: 4-Benzylpyridin ; 4-Benzylpyridine ; Pyridine, 4- (phenylmethyl)- ; Pyridine, 4-(phenylmethyl)- 
Product Categories: Pyridines, Pyrimidines, Purines and Pteredines;C9 to C46;Heterocyclic Building Blocks;Pyridines
Molecular Structure of 4-Benzylpyridine (CAS NO.2116-65-6) :
Molecular Formula of 4-Benzylpyridine (CAS NO.2116-65-6) : C12H11N
Molecular Weight of 4-Benzylpyridine (CAS NO.2116-65-6) : 169.22
CAS NO: 2116-65-6
EINECS : 218-319-0
Index of Refraction: 1.576
Surface Tension: 41.9 dyne/cm
Density: 1.044 g/cm3
Flash Point: 115 °C
Enthalpy of Vaporization: 50.31 kJ/mol
Boiling Point: 285.1 °C at 760 mmHg
Vapour Pressure: 0.00492 mmHg at 25°C
Melting point: 9-11 °C
Storage temp: Indoors
Appearance:clear slightly yellow liquid
Solubility: soluble in ethanol, ethyl ether, insoluble in water.

Uses

 4-Benzylpyridine (CAS NO.2116-65-6) is used as intermediates of medicines and dyes .

Production

Preparation Products: 4-(4-Nitrobenzyl)pyridine
Raw materials: Benzyl chloride 
 4-Benzylpyridine (CAS NO.2116-65-6) is obtained  by preparation of Benzyl chloride and Pyridine .

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
bird - wild LD50 oral 18mg/kg (18mg/kg)   Toxicology and Applied Pharmacology. Vol. 21, Pg. 315, 1972.
mouse LD50 intravenous 25mg/kg (25mg/kg)   U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#12240,
mouse LD50 oral 630uL/kg (0.63mL/kg) BEHAVIORAL: TREMOR

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

GASTROINTESTINAL: ULCERATION OR BLEEDING FROM STOMACH
National Technical Information Service. Vol. OTS0570988,
rat LD50 oral 560uL/kg (0.56mL/kg) SENSE ORGANS AND SPECIAL SENSES: CHROMODACYRORREA: EYE

BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"
National Technical Information Service. Vol. OTS0570988,

 

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by ingestion and intravenous routes. A flammable material. Incompatible with oxidizers. When heated to decomposition it emits toxic fumes of NOx.
Hazard Codes HarmfulXn
Risk Statements 22-36/37/38
R22:Harmful if swallowed. 
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements 26-36
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36:Wear suitable protective clothing.
WGK Germany 3
RTECS US2625000
HS Code 29333999