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21324-40-3

Basic Information
CAS No.: 21324-40-3
Name: Phosphate(1-),hexafluoro-, lithium (1:1)
Article Data: 12
Cas Database
Molecular Structure:
Molecular Structure of 21324-40-3 (Phosphate(1-),hexafluoro-, lithium (1:1))
Formula: F6LiP
Molecular Weight: 151.905
Synonyms: Lithiumhexafluorophosphate (7CI);Phosphate(1-), hexafluoro-, lithium (8CI,9CI);Lithium fluophosphate;Lithium hexafluorophosphate (LiPF6);Lithiumhexafluorophosphate(1-);Lithium phosphorus fluoride (LiPF6);Phosphate(1-), hexafluoro-, lithium;Phosphate(1-), hexafluoro-, lithium (1:1);
EINECS: 244-334-7
Density: 1.5
Melting Point: 200 °C (dec.)(lit.)
Boiling Point: N/A
Flash Point: N/A
Solubility: soluble in water
Appearance: white crystalline powder
Hazard Symbols: CorrosiveC; IrritantXi; ToxicT
Risk Codes: 34-24-22
Safety: 26-36/37/39-45-28A
Transport Information: UN 3260 8/PG 1
PSA: 13.59000
LogP: 3.38240
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Specification

The Phosphate(1-),hexafluoro-, lithium (1:1), with the CAS registry number 21324-40-3 and EINECS registry number 244-334-7, has the systematic name of lithium hexafluorophosphate. And the molecular formula of this chemical is F6LiP. It is a kind of white crystalline powder which is also hygroscopic, and belongs to the following product categories: Inorganic Fluorides; Classes of Metal Compounds; Li (Lithium) Compounds; Typical Metal Compounds; Electrolytes Synthetic Reagents; Alternative Energy; Inorganic Salts; Lithium Salts; Lithium Metal and Ceramic Science; Materials Science; Salts; Synthetic Reagents. Besides, it is the electrolyte materials of lithium ion battery.

The physical properties of Phosphate(1-),hexafluoro-, lithium (1:1) are as following: (1)H-Bond Donor: 0; (2)H-Bond Acceptor: 7; (3)Rotatable Bond Count: 0; (4)Exact Mass: 151.980185; (5)MonoIsotopic Mass: 151.980185; (6)Topological Polar Surface Area: 0; (7)Heavy Atom Count: 8; (8)Formal Charge: 0; (9)Complexity: 67.1; (10)Isotope Atom Count: 0; (11)Defined Atom StereoCenter Count: 0; (12)Undefined Atom StereoCenter Count: 0; (13)Defined Bond StereoCenter Count: 0; (14)Undefined Bond StereoCenter Count: 0; (15)Covalently-Bonded Unit Count: 2.

Preparation of Phosphate(1-),hexafluoro-, lithium (1:1) (Wet method): Dissolve the lithium salts in the anhydrous hydrofluoric acid, and gives LiF.HF solution. Pass PF5 gas, and gives the lithium hexafluorophosphate crystals. Then the desired product can be obtained after separation and drying.

You should be cautious while dealing with this chemical. It isarmful if swallowed and toxic in contact with skin. It may also cause burns. Therefore, you had better take the following instructions: Wear suitable protective clothing, gloves and eye/face protection, and in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice; After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer); In case of accident or if you feel unwell, seek medical advice immediately (show label where possible).

You can still convert the following datas into molecular structure:
(1)SMILES: [Li+].F[P-](F)(F)(F)(F)F
(2)InChI: InChI=1/F6P.Li/c1-7(2,3,4,5)6;/q-1;+1
(3)InChIKey: AXPLOJNSKRXQPA-UHFFFAOYAJ