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23364-44-5

Basic Information
CAS No.: 23364-44-5
Name: (1S,2R)-2-Amino-1,2-diphenylethanol
Article Data: 112
Cas Database
Molecular Structure:
Molecular Structure of 23364-44-5 ((1S,2R)-2-Amino-1,2-diphenylethanol)
Formula: C14H15NO
Molecular Weight: 213.279
Synonyms: (1S,2R)-2-Amino-1,2-diphenyl-ethanol;Racemic-(1S,2R)-2-amino-1,2-diphenylethan-1-ol;Benzeneethanol, β-amino-α-phenyl-, (αS,βR)-;
EINECS: 628-513-0
Density: 1.148 g/cm3
Melting Point: 142-144 ºC
Boiling Point: 374.3 ºC at 760 mmHg
Flash Point: 180.2 ºC
Solubility: N/A
Appearance: white to light yellow crystal powde
Hazard Symbols: HarmfulXn;IrritantXi
Risk Codes: 36/37/38-20/21/22
Safety: 26-36
Transport Information: N/A
PSA: 46.25000
LogP: 3.12030
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Specification

The IUPAC name of this chemical is (1S,2R)-2-Amino-1,2-diphenylethanol. With the CAS registry number 23364-44-5, it is also named as benzeneethanol, β-amino-α-phenyl-, (αS,βR)-. In addition, the molecular formula is C14H15NO and the molecular weight is 213.28. It is a kind of white to light yellow crystal powder and belongs to the classes of Chiral reagent; Amino Alcohols (Chiral); Chiral Building Blocks; Optical Resolution; Synthetic Organic Chemistry; Chiral Chemicals; Chiral Compound; Benzene derivatives; Amino Alcohols; Organic Building Blocks. What's more, it should be stored in a airtight, cool and dry place.

Physical properties about this chemical are: (1)ACD/LogP: 2.28; (2)#H bond acceptors: 2; (3)#H bond donors: 3; (4)#Freely Rotating Bonds: 5; (5)Polar Surface Area: 12.47 Å2; (6)Index of Refraction: 1.621; (7)Molar Refractivity: 65.36 cm3; (8)Molar Volume: 185.6 cm3; (9)Polarizability: 25.91 ×10-24cm3; (10)Surface Tension: 52.2 dyne/cm; (11)Density: 1.148 g/cm3; (12)Flash Point: 180.2 °C; (13)Enthalpy of Vaporization: 65.58 kJ/mol; (14)Boiling Point: 374.3 °C at 760 mmHg; (15)Vapour Pressure: 2.88E-06 mmHg at 25°C.

Preparation of (1S,2R)-2-Amino-1,2-diphenylethanol: it can be prepared by erythro-2-amino-1,2-diphenylethanol. The yield is about 46%.

(1S,2R)-2-Amino-1,2-diphenylethanol can be prepared by erythro-2-amino-1,2-diphenylethanol

Uses of (1S,2R)-2-Amino-1,2-diphenylethanol: it can react with propan-2-one to get 2,2-dimethyl-4,5-diphenyl-oxazolidine. This reaction will need reagents Al powder and acetyl chloride, and solvent CH2Cl2. The reaction time is 20 hours at reaction temperature of 20 °C. The yield is about 80%.

(1S,2R)-2-Amino-1,2-diphenylethanol can react with propan-2-one to get 2,2-dimethyl-4,5-diphenyl-oxazolidine

When you are using this chemical, please be cautious about it as the following:
This chemical is harmful by inhalation, in contact with skin and if swallowed. It is irritating to eyes, respiratory system and skin. Whenever you will contact it, please wear suitable protective clothing. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)SMILES: O[C@@H](c1ccccc1)[C@@H](c2ccccc2)N
(2)InChI: InChI=1/C14H15NO/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10,13-14,16H,15H2/t13-,14+/m1/s1
(3)InChIKey: GEJJWYZZKKKSEV-KGLIPLIRBB

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