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24151-93-7

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Basic Information
CAS No.: 24151-93-7
Name: PIPEROPHOS
Article Data: 1
Molecular Structure:
Molecular Structure of 24151-93-7 (PIPEROPHOS)
Formula: C14H28 N O3 P S2
Molecular Weight: 353.487
Synonyms: Phosphorodithioicacid, O,O-dipropyl ester, S-ester with 1-(mercaptoacetyl)-2-pipecoline (8CI);2-Pipecoline, 1-(mercaptoacetyl)-, S-ester with O,O-dipropyl phosphorodithioate(8CI); C 19490; N-(O,O-Dipropyl-dithiophosphorylacetyl)-2-methylpiperidine;Piperophos; S-(2-Methyl-1-piperidylcarbonylmethyl) O,O-dipropyl phosphorodithioate
EINECS:
Annex I Index No: 015-133-00-X

Phys

Density: 1.153g/cm3
Melting Point: <25℃
Boiling Point: 445.1°Cat760mmHg
Flash Point: 223°C
Solubility: Toxicity data
(The meaning of any abbreviations which appear"> slight

Stability

    Stable. Incompatible with strong oxidizing agents.

Toxicology

    Harmful if swallowed.

    Toxicity data
    (The meaning of any abbreviations which appear

Appearance: dark brown liquid
Hazard Symbols: Xn,N
Risk Codes: 8395577
Safety: A poison by ingestion and intraperitoneal routes. Moderately toxic by inhalation, intramuscular, and skin contact routes. When heated to decomposition it emits toxic vapors of NOx, POx, and SOx.
PSA: 105.97000
LogP: 4.78680
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Chemistry

IUPAC Name: 2-Dipropoxyphosphinothioylsulfanyl-1-(2-methylpiperidin-1-yl)ethanone
Product Categories: OrganophosphorousAlphabetic;Alpha sort;Herbicides;N-PPesticides&Metabolites;P;PER - POLA;Pesticides&Metabolites
Synonyms: 1-(Di-N-Propoxyphosphinothioylthiomethylcarbonyl)-2-methylpiperidine ; Dithiophosphate de S-[2-(2-méthyl-1-pipéridinyl)-2-oxoéthyle] et de O,O-dipropyle ; Phosphorodithioic acid, S-[2-(2-methyl-1-piperidinyl)-2-oxoethyl] O,O-dipropyl ester ; S-(2-(2-Methyl-1-piperidinyl)-2-oxoethyl) O,O-dipropyl phosphorodithioate (9CI)
CAS NO: 24151-93-7
Molecular Formula of Piperophos (CAS NO.24151-93-7) : C14H28NO3PS2
Molecular Weight of Piperophos (CAS NO.24151-93-7) : 353.48
Molecular Structure of Piperophos (CAS NO.24151-93-7) :
Index of Refraction: 1.525
Surface Tension: 45.6 dyne/cm
Density: 1.153 g/cm3
Flash Point: 223 °C
Enthalpy of Vaporization: 70.3 kJ/mol
Boiling Point: 445.1 °C at 760 mmHg
Vapour Pressure: 4.06E-08 mmHg at 25°
Storage temp: 0-6°C
Stability: Stable. Incompatible with strong oxidizing agents.
Appearance:dark brown liquid

Uses

 Piperophos (CAS NO.24151-93-7) is used as herbicide.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intramuscular 1260mg/kg (1260mg/kg)   Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. Vol. 16, Pg. 713, 1991.
mouse LD50 intraperitoneal 250mg/kg (250mg/kg)   Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. Vol. 16, Pg. 713, 1991.
mouse LD50 oral 330mg/kg (330mg/kg)   Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. Vol. 16, Pg. 713, 1991.
mouse LD50 subcutaneous 3300mg/kg (3300mg/kg)   Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. Vol. 16, Pg. 713, 1991.
rat LC50 inhalation > 1960mg/m3/1H (1960mg/m3)   Pesticide Manual. Vol. 9, Pg. 688, 1991.
rat LD50 intramuscular 2520mg/kg (2520mg/kg)   Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. Vol. 16, Pg. 713, 1991.
rat LD50 intraperitoneal 94mg/kg (94mg/kg)   Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. Vol. 16, Pg. 713, 1991.
rat LD50 oral 324mg/kg (324mg/kg)   "Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revisionVol. 2, Pg. 107, 1977.
rat LD50 skin > 2150mg/kg (2150mg/kg)   Pesticide Manual. Vol. 9, Pg. 688, 1991.
rat LD50 subcutaneous > 6gm/kg (6000mg/kg)   Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. Vol. 16, Pg. 713, 1991.

Safety Profile

A poison by ingestion and intraperitoneal routes. Moderately toxic by inhalation, intramuscular, and skin contact routes. When heated to decomposition it emits toxic vapors of NOx, POx, and SOx.
Hazard CodesHarmfulXn,DangerousN
Risk Statements 22-50/53 
R22:Harmful if swallowed. 
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements 60-61
S60:This material and its container must be disposed of as hazardous waste. 
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR 3018
RTECS TE3690000
HazardClass 6.1(b)
PackingGroup III