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4808-30-4

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Basic Information
CAS No.: 4808-30-4
Name: BIS(TRI-N-BUTYLTIN)SULFIDE
Article Data: 21
Molecular Structure:
Molecular Structure of 4808-30-4 (BIS(TRI-N-BUTYLTIN)SULFIDE)
Formula: C24H54 S Sn2
Molecular Weight: 612.179
Synonyms: Bis(tributyltin)sulfide (6CI); Distannathiane, hexabutyl- (9CI); Distannthiane, hexabutyl-(8CI); Tin, thiobis[tributyl- (7CI); Bis(tri-n-butyltin) sulfide;Bis(tributylstannyl) sulfide; Harpp's reagent; Reagents, Harpp's; Tributyltinsulfide
Density: g/cm3
Boiling Point: °Cat760mmHg
Flash Point: °C
Hazard Symbols: Moderately toxic by ingestion. TWA 0.1 mg(Sn)/m3; STEL 0.2 mg/m3 (skin)
Risk Codes: 20/21/22-36/37/38
Safety: Poison by intraperitoneal route. Moderately toxic by ingestion. When heated to decomposition it emits toxic fumes of SOx and Sn.

Analytical Methods:

   

For occupational chemical analysis use NIOSH: Organotin Compounds 5504.

PSA: 25.30000
LogP: 10.41120
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Chemistry

IUPAC Name: Distannathiane, 1,1,1,3,3,3-hexabutyl-
The MF of Distannathiane, 1,1,1,3,3,3-hexabutyl- (4808-30-4) is C24H54SSn2.

                                   
The MW of Distannathiane, 1,1,1,3,3,3-hexabutyl- (4808-30-4) is 612.17.
Synonyms of Distannathiane, 1,1,1,3,3,3-hexabutyl- (4808-30-4): 1,1,1,3,3,3-Hexabutyldistannthiane ; Bis(tributyltin)sulfide ;  Hexabutyl-distannthian ; Thiobis(tributyl-ti ; Tributyltinsulfide ; Bis(tri-N-butyltin)sulfide
Product Categories: Classes of Metal Compounds;Sn (Tin) Compounds;Sulfur Compounds (for Synthesis);Synthetic Organic Chemistry;Typical Metal Compounds
Flash Point: 256.1 °C
Boiling Point: 499.8 °C
Density: 1,518 g/ml
Refractive index: 1.518 
EINECS: 225-369-7

Toxicity Data With Reference

1.    

orl-mus LDLo:470 mg/kg

     AECTCV    Archives of Environmental Contamination and Toxicology. 14 (1985),111.
2.    

ipr-mus LD50:144 mg/kg

     RPTOAN    Russian Pharmacology and Toxicology. Translation of FATOAO. 42 (1979),73.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by intraperitoneal route. Moderately toxic by ingestion. When heated to decomposition it emits toxic fumes of SOx and Sn.Safety information of Distannathiane, 1,1,1,3,3,3-hexabutyl- (4808-30-4):
Risk Statements 
20/21/22  Harmful by inhalation, in contact with skin and if swallowed
36/37/38  Irritating to eyes, respiratory system and skin
Safety Statements 
26  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36/37/39  Wear suitable protective clothing, gloves and eye/face protection
RIDADR  2788
RTECS  JN8830000
TSCA  Yes

Standards and Recommendations

OSHA PEL: TWA 0.1 mg(Sn)/m3
ACGIH TLV: TWA 0.1 mg(Sn)/m3; STEL 0.2 mg/m3 (skin)
NIOSH REL: (Organotin Compounds) 10H TWA 0.1 mg(Sn)/m3

Analytical Methods

For occupational chemical analysis use NIOSH: Organotin Compounds 5504.