CAS No.5089-33-8,4-BROMO-N,N-BIS(TRIMETHYLSILYL)ANILINE Suppliers

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Basic Information

Molecular Structure:
CAS No.:	5089-33-8
Name:	4-BROMO-N,N-BIS(TRIMETHYLSILYL)ANILINE
Article Data:	14
Cas Database

Formula:	C₁₂H₂₂BrNSi₂
Molecular Weight:	316.388
Synonyms:	Disilazane,2-(p-bromophenyl)-1,1,1,3,3,3-hexamethyl- (7CI,8CI);4-Bromo-N,N-bis(trimethylsilyl)aniline;N,N-Bis(trimethylsilyl)-4-bromoaniline;N,N-Bis(trimethylsilyl)-4-bromobenzenamine;N,N-Bis(trimethylsilyl)-p-bromoaniline;N-(4-Bromophenyl)-1,1,1-trimethyl-N-(trimethylsilyl)silanamine;p-Bromo-N,N-bis(trimethylsilyl)aniline;Benzenamine, 4-bromo-N,N-bis(trimethylsilyl)-;N-(4-Bromophenyl)-1,1,1-trimethyl-N-(trimethylsilyl)silanamine;
Density:	1.125 g/cm³
Boiling Point:	298.5 °C at 760 mmHg
Flash Point:	134.3 °C
Hazard Symbols:	Xi
Risk Codes:	36/37/38
Safety:	26-36
PSA:	3.24000
LogP:	4.92530

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Specification

The Silanamine,N-(4-bromophenyl)-1,1,1-trimethyl-N-(trimethylsilyl)-, with the CAS registry number 5089-33-8, has the systematic name of N-(4-bromophenyl)-1,1,1-trimethyl-N-(trimethylsilyl)silanamine. It belongs to the product following product categories: Nitrogen Compounds; Organic Building Blocks; Protected Amines. And the molecular formula of the chemical is C₁₂H₂₂BrNSi₂.

The characteristics of Silanamine,N-(4-bromophenyl)-1,1,1-trimethyl-N-(trimethylsilyl)- are as followings: (1)ACD/LogP: 5.05; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): 4.73; (4)ACD/LogD (pH 7.4): 5.04; (5)ACD/BCF (pH 5.5): 1935.32; (6)ACD/BCF (pH 7.4): 3992.47; (7)ACD/KOC (pH 5.5): 6356; (8)ACD/KOC (pH 7.4): 13112.11; (9)#H bond acceptors: 1; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 3; (12)Polar Surface Area: 3.24 Å²; (13)Index of Refraction: 1.511; (14)Molar Refractivity: 84.22 cm³; (15)Molar Volume: 281.1 cm³; (16)Polarizability: 33.38×10^-24cm³; (17)Surface Tension: 26.4 dyne/cm; (18)Density: 1.125 g/cm³; (19)Flash Point: 134.3 °C; (20)Enthalpy of Vaporization: 53.84 kJ/mol; (21)Boiling Point: 298.5 °C at 760 mmHg; (22)Vapour Pressure: 0.00127 mmHg at 25°C.

Preparation of Silanamine,N-(4-bromophenyl)-1,1,1-trimethyl-N-(trimethylsilyl)-: This chemical can be prepared by 4-bromo-aniline andchloro-trimethyl-silane. The reaction will need reagent BuLi, and the menstruum tetrahydrofuran and hexane. And the yield is about 68%.

Uses of Silanamine,N-(4-bromophenyl)-1,1,1-trimethyl-N-(trimethylsilyl)-: It can react with N-(2-chloro-ethyl)-benzamide to produce N-(4-amino-phenethyl)-benzamide. This reaction will need reagent buthyllithium and lithium naphthalenide, and the menstruum tetrahydrofuran and hexane. And the yield is about 53%.

You should be cautious while dealing with this chemical. It irritates to eyes, respiratory system and skin. Therefore, you had better take the following instructions: Wear suitable protective clothing, and if in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice.

Addtionally, the following datas could be converted into the molecular structure:
(1)SMILES: Brc1ccc(N([Si](C)(C)C)[Si](C)(C)C)cc1
(2)InChI: InChI=1/C12H22BrNSi2/c1-15(2,3)14(16(4,5)6)12-9-7-11(13)8-10-12/h7-10H,1-6H3
(3)InChIKey: YJYMZGDBOMZWSR-UHFFFAOYAV