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5345-54-0

Basic Information
CAS No.: 5345-54-0
Name: Benzenamine,3-chloro-4-methoxy-
Article Data: 25
Cas Database
Molecular Structure:
Molecular Structure of 5345-54-0 (Benzenamine,3-chloro-4-methoxy-)
Formula: C7H8 Cl N O
Molecular Weight: 157.6
Synonyms: p-Anisidine,3-chloro- (7CI,8CI); 2-Chloro-4-aminoanisole; 3-Chloro-4-(methyloxy)aniline;3-Chloro-4-anisidine; 3-Chloro-4-methoxyaniline; 3-Chloro-4-methoxybenzenamine;3-Chloro-4-methoxyphenylamine; 3-Chloro-p-anisidine; 4-Methoxy-3-chloroaniline;NSC 1706
EINECS: 226-298-4
Density: 1.234 g/cm3
Melting Point: 50-55 °C(lit.)
Boiling Point: 271.1 °C at 760 mmHg
Flash Point: >230 °F
Solubility: N/A
Appearance: UN 2233 6.1/PG 3
Hazard Symbols:
Risk Codes: R22   
Safety: Moderately toxic by ingestion and intraperitoneal routes. A skin and eye irritant. When heated to decomposition it emits toxic fumes of Cl and NOx. See also AROMATIC AMINES.
Transport Information: UN 2233
PSA: 35.25000
LogP: 2.51200
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  • 3-Chloro-4-methoxyaniline  5345-54-0  C7H8ClNO   C7H8ClNO

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Chemistry

Molecular Formula:C7H8ClNO
Molar mass:157.59752g/mol
Structure of 3-Chloro-4-methoxyaniline(5345-54-0):
                      
Synonyms of 3-Chloro-4-methoxyaniline(5345-54-0):3-Chloro-p-anisidine;2-Chloro-4-anisidine ;Benzenamine, 3-chloro-4-methoxy-;2-Chloro-4-aminoanisole;3-Chloro-4-methoxybenzenamine;Orthochloroparanisidine;p-Anisidine, 3-chloro-;3-Chloroanisidine
OCPA
Density:1.234 g/cm3                              
Flash Point:117.7 °C               
Boiling Point:271.1 °C at 760 mmHg            
Index of Refraction:157.59752
Vapour Pressure:0.00659 mmHg at 25°C      
Melting point:50-55 °C(lit.)

Uses

3-Chloro-4-methoxyaniline(5345-54-0) can be used as intermediates in organic synthesis.

Toxicity Data With Reference

1.   

skn-rbt 500 mg/24H MLD

   TOERD9    Toxicological European Research. 2 (1979),77.
2.   

eye-rbt 100 mg MLD

   TOERD9    Toxicological European Research. 2 (1979),77.
3.   

orl-rat LD50:550 mg/kg

   TOERD9    Toxicological European Research. 2 (1979),77.
4.   

ipr-rat LD50:510 mg/kg

   TOERD9    Toxicological European Research. 2 (1979),77.
5.   

orl-mus LD50:650 mg/kg

   TOERD9    Toxicological European Research. 2 (1979),77.
6.   

ipr-mus LD50:670 mg/kg

   TOERD9    Toxicological European Research. 2 (1979),77.
Carcinogenicity:3-Chloro-4-methoxyaniline(5345-54-0)- Not listed as a carcinogen by  NTP, IARC,ACGIH, or CA Prop 65. 
Other: See actual entry in RTECS for complete information.The toxicological properties have not been fully investigated. Mutagenicity: Ames-test: negative.

Safety Profile


Moderately toxic by ingestion and intraperitoneal routes. A skin and eye irritant. When heated to decomposition it emits toxic fumes of Cl− and NOx. See also AROMATIC AMINES.
Hazard Codes:Xn,Xi
Risk Statements:
22:  Harmful if swallowed 
Safety Statements:
24:  Avoid contact with skin
25:  Avoid contact with eyes

Specification

Stability and Reactivity of 3-Chloro-4-methoxyaniline(5345-54-0):
Conditions to Avoid:Incompatible materials. 
Chemical Stability:Stable under normal pressures and temperatures.
Incompatibilities with Other Materials: strong oxidizing agents.
Hazardous Decomposition Products: carbon dioxide,nitrogen oxides, hydrogen bromide,Carbon monoxide.