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56-97-3

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Basic Information
CAS No.: 56-97-3
Name: 1,1'-TRIMETHYLENE-BIS(4-FORMYLPYRIDINIUM BROMIDE) DIOXIME
Article Data: 6
Molecular Structure:
Molecular Structure of 56-97-3 (1,1'-TRIMETHYLENE-BIS(4-FORMYLPYRIDINIUM BROMIDE) DIOXIME)
Formula: C15H18 N4 O2 . 2 Br
Molecular Weight: 446.142
Synonyms: 1,1'-Trimethylenebis[4-formylpyridiniumbromide] dioxime (6CI); Pyridinium,1,1'-(1,3-propanediyl)bis[4-[(hydroxyimino)methyl]-, dibromide (9CI);Pyridinium, 1,1'-trimethylenebis[4-formyl-, dibromide, dioxime (8CI);1,1-Trimethylenebis(4-formylpyridine oxime) dibromide;1,1'-Trimethylenebis(4-aldoximinopyridinium) dibromide; 1,1'-Trimethylenebis(4-formylpyridinebromide) dioxime; 1,1'-Trimethylenebis(4-formylpyridinium) dibromide dioxime;1,3-Bis(4-hydroxyiminomethyl-1-pyridinium)propane dibromide;1,3-Bis(4-hydroxyiminomethylpyridinium)propane dibromide; 1,3-Bis(4-hydroxyiminomethylpyridino)propanedibromide; 1,3-Bis(N-pyridine-4-aldoxime)propane dibromide;1,3-Bis(pyridinium-4-aldoxime)propane dibromide;1,3-Trimethylenebis(4-hydroxyiminomethylpyridinium bromide); C 434; Dipiroxim;Dipiroxim dibromide; Dipiroxime; Dipyroxim dibromide;N,N'-Trimethylenebis(4-formylpyridinium bromide) dioxime;N,N'-Trimethylenebis(pyridinium-4-aldoxime) dibromide; TMB 4; TMB 4(pharmaceutical); Trimedoxime; Trimedoxime N; Trimedoxime bromide;Trimethylenebis(4-hydroxyiminomethylpyridinium) dibromide
Density: g/cm3
Melting Point: 231 °C (dec.)(lit.)
Boiling Point: 412.9°Cat760mmHg
Flash Point: 203.5°C
Hazard Symbols: Xi
Risk Codes: R36/37/38
Safety: Poison by intraperitoneal, intramuscular, subcutaneous, and intravenous routes. When heated to decomposition it emits very toxic fumes of NOx and Br−. Used as an antidote for organophosphate poisoning. See also BROMIDES.
PSA: 72.94000
LogP: -5.02390
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Toxicity Data With Reference

1.   

ipr-rat LD50:192 mg/kg

    RPTOAN    Russian Pharmacology and Toxicology. Translation of FATOAO. 38 (4)(1975),168.
2.   

ivn-rat LD50:89 mg/kg

    JPETAB    Journal of Pharmacology and Experimental Therapeutics. 129 (1960),31.
3.   

ims-rat LD50:123 mg/kg

    JPETAB    Journal of Pharmacology and Experimental Therapeutics. 129 (1960),31.
4.   

ipr-mus LD50:53,500 µg/kg

    RPTOAN    Russian Pharmacology and Toxicology. Translation of FATOAO. 38 (4)(1975),168.
5.   

scu-mus LD50:83 mg/kg

    RPTOAN    Russian Pharmacology and Toxicology. Translation of FATOAO. 35 (5)(1972),243.
6.   

ivn-mus LD50:45 mg/kg

    ARZNAD    Arzneimittel-Forschung. Drug Research. 14 (1964),870.
7.   

ims-mus LD50:102 mg/kg

    ARZNAD    Arzneimittel-Forschung. Drug Research. 14 (1)(1964),5.
8.   

ims-cat LD50:117 mg/kg

    RPTOAN    Russian Pharmacology and Toxicology. Translation of FATOAO. 38 (4)(1975),168.
9.   

ivn-rbt LD50:44 mg/kg

    AEHLAU    Archives of Environmental Health. 5 (1962),21.

Safety Profile

Poison by intraperitoneal, intramuscular, subcutaneous, and intravenous routes. When heated to decomposition it emits very toxic fumes of NOx and Br−. Used as an antidote for organophosphate poisoning. See also BROMIDES.