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| CAS No.: | 607-57-8 |
|---|---|
| Name: | 2-Nitrofluorene |
| Article Data: | 38 |
| Molecular Structure: | |
|
|
|
| Formula: | C13H9NO2 |
| Molecular Weight: | 211.22 |
| Synonyms: | Fluorene,2-nitro- (6CI,7CI,8CI);2-Nitro-9H-fluorene;2-Nitrofluorene;NSC 5182; |
| EINECS: | 210-138-5 |
| Density: | 1.318 g/cm3 |
| Melting Point: | 156-158 °C(lit.) |
| Boiling Point: | 374.7 °C at 760 mmHg |
| Flash Point: | 185.2 °C |
| Solubility: | Insoluble in water |
| Appearance: | cream powder |
| Hazard Symbols: |
 Xn
|
| Risk Codes: | 40-68 |
| Safety: | 36/37 |
| Transport Information: | UN 3077 9/PG 3 |
| PSA: | 45.82000 |
| LogP: | 3.68920 |
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Chemistry
IUPAC Name: 2-Nitrofluorene
The MF of 2-Nitrofluorene (607-57-8) is C13H9NO2.
The MW of 2-Nitrofluorene (607-57-8) is 211.22.
Synonyms of 2-Nitrofluorene (607-57-8): 2-Nitrofluorene ; 9H-Fluorene, 2-nitro- ; 2-Nitro-9H-fluorene ; Fluorene, 2-nitro- ; Fluorene, 2-nitro- (8CI)
Product Categories: Fluorene Derivatives;Fluorenes;Fluorenes & Fluorenones;Nitro Compounds;Nitrogen Compounds;Organic Building Blocks
Form: Cream-colored solid
Index of Refraction: 1.677
EINECS: 210-138-5
Density: 1.318 g/ml
Flash Point: 185.2 °C
Boiling Point: 374.7 °C
Melting Point: 156 °C
Water Solubility: Insoluble
Stability: Stable
Uses
2-Nitrofluorene (607-57-8) is used as organic synthesis intermediates.
Production
Aromatic nitro compounds, such as 2-Nitrofluorene, range from slight to strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. The aromatic nitro compounds may explode in the presence of a base such as sodium hydroxide or potassium hydroxide even in the presence of water or organic solvents. The explosive tendencies of aromatic nitro compounds are increased by the presence of multiple nitro groups. Stable under normal conditions. Protect from bases.
Toxicity Data With Reference
| 1. | mmo-sat 250 ng/plate | MUREAV Mutation Research. 143 (1985),213. | ||
| 2. | otr-hmn:lvr 80 µg/L | BJCAAI British Journal of Cancer. 37 (1978),873. | ||
| 3. | skn-rat TDLo:310 mg/kg/79W-I:NEO | JNCIAM Journal of the National Cancer Institute. 10 (1950),1201. | ||
| 4. | ipr-mus LD50:1600 mg/kg | JJIND8 JNCI, Journal of the National Cancer Institute. 62 (1979),911. |
Consensus Reports
IARC Cancer Review: Group 2B IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 46 ,1989,p. 291.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Sufficient Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 46 ,1989,p. 277.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Human No Adequate Data IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 46 ,1989,p. 277.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.
Safety Profile
Confirmed carcinogen with experimental carcinogenic and tumorigenic data. Moderately toxic by intraperitoneal route. Human mutation data reported. When heated to decomposition it emits toxic fumes of NOx. See also NITRO COMPOUNDS of AROMATIC HYDROCARBONS.
Safety information of 2-Nitrofluorene (607-57-8):
Hazard Codes .gif){kind=small}
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N
Risk Statements
40 Limited evidence of a carcinogenic effect
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
68 Possible risk of irreversible effects
Safety Statements
36/37 Wear suitable protective clothing and gloves
61 Avoid release to the environment. Refer to special instructions safety data sheet
RIDADR UN 3077 9/PG 3
WGK Germany 3
RTECS LL8225000
HS Code 29042000