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683-85-2

Basic Information
CAS No.: 683-85-2
Name: DIMETHYLPHOSPHORAMIDOUS DICHLORIDE
Article Data: 3
Molecular Structure:
Molecular Structure of 683-85-2 (DIMETHYLPHOSPHORAMIDOUS DICHLORIDE)
Formula: C2H6Cl2NP
Molecular Weight: 145.956
Synonyms: Dimethylphosphoramidous dichloride;(Dimethylamino)dichlorophosphine;Dimethylphosphoramidousdichlorid;Phosphoramidous dichloride, dimethyl-;
Density: 1.271 g/mL at 25 °C(lit.)
Boiling Point: 132.2 °C at 760 mmHg
Flash Point: 33.8 °C
Solubility: Reacts with water.
Appearance: Colorless to light yellow liquid
Hazard Symbols: FlammableF,CorrosiveC
Risk Codes: 11-14-34
Safety: 16-23-26-27-36/37/39-45
Transport Information: UN 2924
PSA: 16.83000
LogP: 2.25250
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Specification

The Phosphoramidousdichloride, N,N-dimethyl-, with the CAS registry number 683-85-2, is also known as Dimethylphosphoramidous dichloride. It belongs to the product categories of Organic Building Blocks; Phosphorus Compounds; Phosphorus Halides. This chemical's molecular formula is C2H6Cl2NP and molecular weight is 145.96. What's more, its IUPAC name is N-dichlorophosphanyl-N-methylmethanamine.

Physical properties of Phosphoramidousdichloride, N,N-dimethyl- are: (1)ACD/LogP: 2.62; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 2.62; (4)ACD/LogD (pH 7.4): 2.62; (5)ACD/BCF (pH 5.5): 57.45; (6)ACD/BCF (pH 7.4): 57.45; (7)ACD/KOC (pH 5.5): 632.27; (8)ACD/KOC (pH 7.4): 632.27; (9)#H bond acceptors: 1; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 1; (12)Polar Surface Area: 16.83 Å2 ; (13)Flash Point: 33.8 °C; (14)Enthalpy of Vaporization: 36.98 kJ/mol; (15)Boiling Point: 132.2 °C at 760 mmHg; (16)Vapour Pressure: 8.95 mmHg at 25°C.

Preparation: this chemical can be prepared by tetra-N-methyl-methanediamine. This reaction will need reagent tetra-N-methyl-methanediamine and solvent benzene with the reaction time of 1 hour. The yield is about 75%.

Phosphoramidousdichloride, N,N-dimethyl- can be prepared by tetra-N-methyl-methanediamine

Uses of Phosphoramidousdichloride, N,N-dimethyl-: it can be used to produce di-2-furyl-N,N-dimethylphosphinous amide at the ambient temperature. It will need reagent Li and solvent tetrahydrofuran. The yield is about 45%.

Phosphoramidousdichloride, N,N-dimethyl- can be used to produce di-2-furyl-N,N-dimethylphosphinous amide at the ambient temperature

When you are using this chemical, please be cautious about it as the following:
This chemical may catch fire in contact with air, only need brief contact with an ignition source. It has a very low flash point or evolves highly flammable gases in contact with water. It may destroy living tissue on contact. What's more, it is highly flammable. The product reacts violently with water. It may cause burns, so you should keep away from sources of ignition - No smoking. Moreover, do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer). In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. You'd better take off immediately all contaminated clothing. When using it, you need wear suitable protective clothing, gloves and eye/face protection. At last ,in case of accident or if you feel unwell seek medical advice immediately (show the label where possible).

You can still convert the following datas into molecular structure:
(1)SMILES: ClP(Cl)N(C)C
(2)Std. InChI: InChI=1S/C2H6Cl2NP/c1-5(2)6(3)4/h1-2H3
(3)Std. InChIKey: XPWWDZRSNFSLRQ-UHFFFAOYSA-N