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Basic Information
CAS No.: 71626-11-4
Name: Benalaxyl
Article Data: 49
Molecular Structure:
Molecular Structure of 71626-11-4 (Benalaxyl)
Formula: C20H23NO3
Molecular Weight: 325.408
Synonyms: Methyl N-(2,6-dimethylphenyl)-N-(phenylacetyl)-DL-alaninate;EPA Pesticide Chemical Code 127001;Methyl N-phenylacetyl-N-2,6-xylyl-DL-alaninate;M 9834;methyl 2-[(2,6-dimethylphenyl)-(2-phenylacetyl)amino]propanoate;Alanine,N-(2,6-dimethylphenyl)-N-(phenylacetyl)-,methyl ester;Benalaxyl [BSI:ISO];Galben;N-(2,6-Dimethylphenyl)-N-(phenylacetyl)-DL-alanine methyl ester;Alanine, N-(2,6-dimethylphenyl)-N-(phenylacetyl)-, methyl ester, DL-;methyl N-(2,6-dimethylphenyl)-N-(phenylacetyl)-D-alaninate;Alanine, N-(2,6-dimethylphenyl)-N-(phenylacetyl)-, methyl ester, DL-;DL-Alanine, N-(2,6-dimethylphenyl)-N-(phenylacetyl)-, methyl ester;
EINECS: 275-728-7
Density: 1.131 g/cm3
Melting Point: 78-80 °C
Boiling Point: 468.8 °C at 760 mmHg
Flash Point: 237.3 °C
Solubility: 28.6 mg l-1 (20 °C)
Appearance: White powder
Hazard Symbols: DangerousN
Risk Codes: 50/53
Safety: 60-61
Transport Information: UN 3077
PSA: 46.61000
LogP: 3.44060
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Specification

The Benalaxyl, with the CAS registry number 71626-11-4 and EINECS registry number 275-728-7, has the systematic name of methyl N-(2,6-dimethylphenyl)-N-(phenylacetyl)-D-alaninate. It belongs to the following product categories: Fungicide; A-BPesticides; Alpha sort; Amide structure Alphabetic; B; BA-BH; Fungicides; Pesticides & Metabolites. And the molecular formula of this chemical is C20H23NO3. What's more, it should be stored at 0-6°C.

The physical properties of Benalaxyl are as following: (1)ACD/LogP: 3.88; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 3.88; (4)ACD/LogD (pH 7.4): 3.88; (5)ACD/BCF (pH 5.5): 522.57; (6)ACD/BCF (pH 7.4): 522.62; (7)ACD/KOC (pH 5.5): 3070.69; (8)ACD/KOC (pH 7.4): 3071.01; (9)#H bond acceptors: 4; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 6; (12)Polar Surface Area: 46.61 Å2; (13)Index of Refraction: 1.574; (14)Molar Refractivity: 94.99 cm3; (15)Molar Volume: 287.6 cm3; (16)Polarizability: 37.66×10-24cm3; (17)Surface Tension: 44.5 dyne/cm; (18)Density: 1.131 g/cm3; (19)Flash Point: 237.3 °C; (20)Enthalpy of Vaporization: 73.11 kJ/mol; (21)Boiling Point: 468.8 °C at 760 mmHg; (22)Vapour Pressure: 5.8E-09 mmHg at 25°C.

Preparation and uses of Benalaxyl: It can be prepared by 2,6-dimethyl amino methyl ester and phenyl chloride. And 2,6-dimethyl amino methyl ester can be obtained start from the reaction between methyl acetate and 2,6-dimethylaniline in the cyclohexane solution. Then the product becomes 2,6-dimethyl amino methyl ester via hydrogenated reduction in the presence of catalyst Raney's nickel, and this reaction need the pressure 20MPa, and the reaction time is 3 hours. In addition, Benalaxyl is often used as systemic fungicide to control phylophthora capsici and downy mildew of garpe.

You should be cautious while dealing with this chemical. It very toxic to aquatic organisms, and may cause long-term adverse effects in the aquatic environment. Therefore, you had better take the following instructions: This material and/or its container must be disposed of as hazardous waste; Avoid release to the environment. Refer to special instructions safety data sheet.

You can still convert the following datas into molecular structure:
(1)SMILES: O=C(N(c1c(cccc1C)C)[C@H](C(=O)OC)C)Cc2ccccc2
(2)InChI: InChI=1/C20H23NO3/c1-14-9-8-10-15(2)19(14)21(16(3)20(23)24-4)18(22)13-17-11-6-5-7-12-17/h5-12,16H,13H2,1-4H3/t16-/m0/s1
(3)InChIKey: CJPQIRJHIZUAQP-INIZCTEOBS

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
chicken LD50 oral 4600mg/kg (4600mg/kg)   Proceedings-British Crop Protection Conference-Pests and Diseases. Vol. -, Pg. 11, 1981.
duck LD50 oral > 6gm/kg (6000mg/kg)   "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc of Chemistry, 1983-86Vol. A795, Pg. 1985,
mouse LD50 oral 680mg/kg (680mg/kg)   Pesticide Manual. Vol. 9, Pg. 51, 1991.
quail LD50 oral 3700mg/kg (3700mg/kg)   "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc of Chemistry, 1983-86Vol. A795, Pg. 1985,
rabbit LD50 skin > 5gm/kg (5000mg/kg)   Farm Chemicals Handbook. Vol. -, Pg. C150, 1991.
rat LC50 inhalation > 10gm/m3/4H (10000mg/m3)   "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc of Chemistry, 1983-86Vol. A795, Pg. 1985,
rat LD50 intraperitoneal 1100mg/kg (1100mg/kg)   "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc of Chemistry, 1983-86Vol. A795, Pg. 1985,
rat LD50 oral 4200mg/kg (4200mg/kg)   "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc of Chemistry, 1983-86Vol. A795, Pg. 1985,
rat LD50 skin > 5gm/kg (5000mg/kg)   Pesticide Manual. Vol. 9, Pg. 51, 1991.