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7205-90-5

Basic Information
CAS No.: 7205-90-5
Name: CHLOROMETHYL 4-CHLOROPHENYL SULFIDE
Article Data: 22
Molecular Structure:
Molecular Structure of 7205-90-5 (CHLOROMETHYL 4-CHLOROPHENYL SULFIDE)
Formula: C7H6 Cl2 S
Molecular Weight: 193.097
Synonyms: Sulfide,chloromethyl p-chlorophenyl (6CI,7CI,8CI); (4-Chlorophenyl)thiomethyl chloride;(p-Chlorophenylthio)methyl chloride; Chloromethyl 4-chlorophenyl sulfide;Chloromethyl p-chlorophenyl sulfide; p-Chlorophenyl chloromethyl sulfide
Density: 1.348 g/mL at 25 °C(lit.)
Boiling Point: 128-129 °C12 mm Hg(lit.)
Flash Point: >230 °F
Risk Codes: R34
Safety: A skin and severe eye irritant. When heated to decomposition it emits very toxic fumes of SOx and Cl. See also MERCAPTANS.
PSA: 25.30000
LogP: 3.62840
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Chemistry

IUPAC Name: Chloromethyl 4-chlorophenyl sulfide
The MF of Chloromethyl 4-chlorophenyl sulfide (CAS NO.7205-90-5) is C7H6Cl2S.

                                          
The MW of Chloromethyl 4-chlorophenyl sulfide (CAS NO.7205-90-5) is 193.09.
Synonyms of Chloromethyl 4-chlorophenyl sulfide (CAS NO.7205-90-5): Benzene, 1-chloro-4-[(chloromethyl)thio]- ; Sulfide, chloromethyl p-chlorophenyl ; Chloromethyl 4-chlorophenyl sulfide 
Product Categories: Organic Building Blocks;Sulfides/Disulfides;Sulfur Compounds
Index of Refraction: 1.601 
EINECS: 230-578-1
Density: 1.34 g/ml 
Flash Point: 103.2 °C 
Boiling Point: 261.9 °C

Uses

  Chloromethyl 4-chlorophenyl sulfide (CAS NO.7205-90-5) is used as three parathion pesticide intermediates.

Production

Adding 35% concentrated hydrochloric acid(200kg)in 500L glass-lined Fan Yingguo,stirring slowly.Adding 30% formaldehyde(30kg) for 20min.Then continue stirring for 15min. Heated to 40 ℃, drip of benzene, chlorobenzene thiophenol solution 85kg, plus heated to 55 ℃ reaction exhausted 2h, cooled to 30 ℃ put it aside for stratification, the upper sulfide water washed twice, under vacuum after the steam to benzene, which may chlorophenyl chloromethyl sulfide.

Toxicity Data With Reference

1.    

skn-rbt 500 mg/24H MOD

    28ZPAK    Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku Marhold, J.V.,Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha,Czechoslovakia.: 1972,172.
2.    

eye-rbt 50 µg/24H SEV

    28ZPAK    Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku Marhold, J.V.,Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha,Czechoslovakia.: 1972,172.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

A skin and severe eye irritant. When heated to decomposition it emits very toxic fumes of SOx and Cl. See also MERCAPTANS.Safety information of Chloromethyl 4-chlorophenyl sulfide (CAS NO.7205-90-5):
Hazard Codes  CorrosiveC
Risk Statements 
34 Causes burns
Safety Statements 
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
27 Take off immediately all contaminated clothing
28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer)
36/37/39 Wear suitable protective clothing, gloves and eye/face protection
45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
RIDADR  UN 3265 8/PG 2
WGK Germany  3
RTECS  CZ0200000
HazardClass  8
PackingGroup  III