CAS No.732-11-6,Phosmet Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	732-11-6
Name:	Phosmet

Formula:	C11H12 N O4 P S2
Molecular Weight:	317.326
Synonyms:	Phosphorodithioicacid, O,O-dimethyl S-phthalimidomethyl ester (6CI); Phosphorodithioic acid,O,O-dimethyl ester, S-ester with N-(mercaptomethyl)phthalimide (8CI);Decemthion; Decemthion EK 20; Decemthion P-6; Decemtion; Fosmet; Ftalophos; GWN1976; Imidan; Imidathion; N-(Mercaptomethyl)phthalimide S-(O,O-dimethyl phosphorodithioate);O,O-Dimethyl S-(phthalimidomethyl) dithiophosphate; O,O-DimethylS-phthalimidomethyl phosphorodithioate; O,O-Dimethyl S-phthalimidomethylphosphorodithioate; Orbisect; Ordatox; PMP; PMP (pesticide); Phosmet;Phthalophos; Porect; Prolate; R 1504; S-Phthalimidomethyl O,O-dimethylphosphorodithioate; Safidon; Simidan; Starbar GX 118; Stauffer R 1504
EINECS:	211-987-4
Density:	1.473g/cm3
Melting Point:	72.5 ºC
Boiling Point:	412.6oC at 760 mmHg
Flash Point:	>100°C
Solubility:	25 mg l-1 (25°C)
Hazard Symbols:
Risk Codes:	R21/22;R50/53
Safety:	A human poison by ingestion. Poison experimentally by inhalation and ingestion routes. Moderately toxic by skin contact. Human systemic effects by inhalation: lachrymation, somnolence, and olfaction effects. Experimental teratogenic and reproductive effects. Mutation data reported. When heated to decomposition it emits very toxic fumes of NO_x, PO_x, and SO_x. See also ESTERS.
Transport Information:	UN 2811
PSA:	123.04000
LogP:	3.07910

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Chemistry

MF: C₁₁H₁₂NO₄PS₂
MW: 317.32
EINECS: 211-987-4
mp: 72.5°C
Fp: >100 °C
storage temp: 0-6°C
CAS DataBase Reference: 732-11-6(CAS DataBase Reference)
NIST Chemistry Reference: 732-11-6(NIST)
The structure of PHTHALIMIDOMETHYL-O,O-DIMETHYL
Synonyms:(O,O-Dimethyl-phthalimidiomethyl-dithiophosphate);Decemthion;Decemthion P-6;decemthionp-6;decemtionp-6;ENT 25,705;ent25,705;ent25705
Molecular Structure of PHOSPHORODITHIOATE is:

Toxicity Data With Reference

1.	mmo-sat 5 mg/plate	MUREAV Mutation Research. 116 (1983),185.
2.	mma-sat 5 mg/plate	MUREAV Mutation Research. 116 (1983),185.
3.	orl-hmn LDLo:50 mg/kg	SPEADM Special Publication of the Entomological Society of America .(College Park, MD.: )1974,74-1.
4.	ihl-hmn TCLo:2 mg/m3/8H:NOSE,EYE,CNS	HYSAAV Hygiene and Sanitation: English Translation of Gigiena Sanitariya. 34 (1969),192.
5.	orl-rat LD50:92,500 µg/kg	GTPZAB Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 14 (12)(1970),46.
6.	ihl-rat LC50:54 mg/m3/4H	85GMAT Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure Izmerov, N.F., et al.,Moscow, USSR.: Centre of International Projects, GKNT,1982,59.
7.	skn-rat LD50:1326 mg/kg	85GMAT Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure Izmerov, N.F., et al.,Moscow, USSR.: Centre of International Projects, GKNT,1982,59.
8.	orl-mus LD50:26 mg/kg	HYSAAV Hygiene and Sanitation: English Translation of Gigiena Sanitariya. 34 (1969),192.
9.	ihl-cat LCLo:65 mg/m3/4H	HYSAAV Hygiene and Sanitation: English Translation of Gigiena Sanitariya.

Consensus Reports

PHTHALIMIDOMETHYL-O,O-DIMETHYL PHOSPHORODITHIOATE is reported in EPA Extremely Hazardous Substances List.

Safety Profile

Hazard Codes: Xn;N,N,Xn
Risk Statements: 21/22-50/53
Safety Statements: 22-36/37-60-61
RIDADR: UN 2811
RTECS: TE2275000
HazardClass: 6.1(b)
PackingGroup: III
A human poison by ingestion. Poison experimentally by inhalation and ingestion routes. Moderately toxic by skin contact. Human systemic effects by inhalation: lachrymation, somnolence, and olfaction effects. Experimental teratogenic and reproductive effects. Mutation data reported. When heated to decomposition PHTHALIMIDOMETHYL-O,O-DIMETHYL PHOSPHORODITHIOATE emits very toxic fumes of NO_x, PO_x, and SO_x.

Specification

Organophosphates, such as Phosmet, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides. Storage above 113 F, may lead to decomposition. [EPA, 1998].